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Dibutyl{N′-[1-(5-chloro-2-oxidophenyl-κO)ethylidene]-3-hydroxy-2-naphthohydrazidato-κ(2) N′,O (2)}tin(IV)
The five-coordinate Sn(IV) atoms in the two crystallographically independent molecules of the title compound, [Sn(C(4)H(9))(2)(C(19)H(13)ClN(2)O(3))], are in distorted cis-C(2)NO(2)Sn trigonal-bipyramidal coordination environments. The tridentate dianion of the Schiff base, N′-[1-(5-chloro-2-oxidop...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006936/ https://www.ncbi.nlm.nih.gov/pubmed/21587723 http://dx.doi.org/10.1107/S1600536810021896 |
| _version_ | 1782194258104549376 |
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| author | Lee, See Mun Mohd Ali, Hapipah Lo, Kong Mun |
| author_facet | Lee, See Mun Mohd Ali, Hapipah Lo, Kong Mun |
| author_sort | Lee, See Mun |
| collection | PubMed |
| description | The five-coordinate Sn(IV) atoms in the two crystallographically independent molecules of the title compound, [Sn(C(4)H(9))(2)(C(19)H(13)ClN(2)O(3))], are in distorted cis-C(2)NO(2)Sn trigonal-bipyramidal coordination environments. The tridentate dianion of the Schiff base, N′-[1-(5-chloro-2-oxidophenyl)ethylidene]-3-hydroxy-2-naphthohydrazide, displays intermolecular O—H⋯N hydrogen bonding, which stabilizes the overall compound. |
| format | Text |
| id | pubmed-3006936 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30069362010-12-30 Dibutyl{N′-[1-(5-chloro-2-oxidophenyl-κO)ethylidene]-3-hydroxy-2-naphthohydrazidato-κ(2) N′,O (2)}tin(IV) Lee, See Mun Mohd Ali, Hapipah Lo, Kong Mun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The five-coordinate Sn(IV) atoms in the two crystallographically independent molecules of the title compound, [Sn(C(4)H(9))(2)(C(19)H(13)ClN(2)O(3))], are in distorted cis-C(2)NO(2)Sn trigonal-bipyramidal coordination environments. The tridentate dianion of the Schiff base, N′-[1-(5-chloro-2-oxidophenyl)ethylidene]-3-hydroxy-2-naphthohydrazide, displays intermolecular O—H⋯N hydrogen bonding, which stabilizes the overall compound. International Union of Crystallography 2010-06-16 /pmc/articles/PMC3006936/ /pubmed/21587723 http://dx.doi.org/10.1107/S1600536810021896 Text en © Lee et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Lee, See Mun Mohd Ali, Hapipah Lo, Kong Mun Dibutyl{N′-[1-(5-chloro-2-oxidophenyl-κO)ethylidene]-3-hydroxy-2-naphthohydrazidato-κ(2) N′,O (2)}tin(IV) |
| title | Dibutyl{N′-[1-(5-chloro-2-oxidophenyl-κO)ethylidene]-3-hydroxy-2-naphthohydrazidato-κ(2)
N′,O
(2)}tin(IV) |
| title_full | Dibutyl{N′-[1-(5-chloro-2-oxidophenyl-κO)ethylidene]-3-hydroxy-2-naphthohydrazidato-κ(2)
N′,O
(2)}tin(IV) |
| title_fullStr | Dibutyl{N′-[1-(5-chloro-2-oxidophenyl-κO)ethylidene]-3-hydroxy-2-naphthohydrazidato-κ(2)
N′,O
(2)}tin(IV) |
| title_full_unstemmed | Dibutyl{N′-[1-(5-chloro-2-oxidophenyl-κO)ethylidene]-3-hydroxy-2-naphthohydrazidato-κ(2)
N′,O
(2)}tin(IV) |
| title_short | Dibutyl{N′-[1-(5-chloro-2-oxidophenyl-κO)ethylidene]-3-hydroxy-2-naphthohydrazidato-κ(2)
N′,O
(2)}tin(IV) |
| title_sort | dibutyl{n′-[1-(5-chloro-2-oxidophenyl-κo)ethylidene]-3-hydroxy-2-naphthohydrazidato-κ(2)
n′,o
(2)}tin(iv) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006936/ https://www.ncbi.nlm.nih.gov/pubmed/21587723 http://dx.doi.org/10.1107/S1600536810021896 |
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