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Bis(1,3-dibenzylimidazolium) μ-oxido-bis[trichloridoferrate(III)]
In the title compound (C(17)H(17)N(2))(2)[Fe(2)Cl(6)O], obtained from the solid-state reaction of FeCl(2) and N,N′-dibenzylimidazolium chloride, the complex anion has approximate D (3d) symmetry with crystallographically imposed inversion symmetry coincident with the bridging μ-O atom. The stereoch...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006938/ https://www.ncbi.nlm.nih.gov/pubmed/21587757 http://dx.doi.org/10.1107/S1600536810024098 |
| Sumario: | In the title compound (C(17)H(17)N(2))(2)[Fe(2)Cl(6)O], obtained from the solid-state reaction of FeCl(2) and N,N′-dibenzylimidazolium chloride, the complex anion has approximate D (3d) symmetry with crystallographically imposed inversion symmetry coincident with the bridging μ-O atom. The stereochemistry about each FeCl(3)O centre is distorted tetrahedral [Fe—Cl = 2.2176 (5)–2.2427 (5) Å and Fe—O = 1.7545 (2) Å]. The Cl atoms are involved in weak anion–cation C—H⋯Cl interactions, giving a network structure. |
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