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Bis(1,3-dibenzylimidazolium) μ-oxido-bis[trichloridoferrate(III)]
In the title compound (C(17)H(17)N(2))(2)[Fe(2)Cl(6)O], obtained from the solid-state reaction of FeCl(2) and N,N′-dibenzylimidazolium chloride, the complex anion has approximate D (3d) symmetry with crystallographically imposed inversion symmetry coincident with the bridging μ-O atom. The stereoch...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006938/ https://www.ncbi.nlm.nih.gov/pubmed/21587757 http://dx.doi.org/10.1107/S1600536810024098 |
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| author | Mutambi, E. M. Adams, C. J. Orpen, A. G. |
| author_facet | Mutambi, E. M. Adams, C. J. Orpen, A. G. |
| author_sort | Mutambi, E. M. |
| collection | PubMed |
| description | In the title compound (C(17)H(17)N(2))(2)[Fe(2)Cl(6)O], obtained from the solid-state reaction of FeCl(2) and N,N′-dibenzylimidazolium chloride, the complex anion has approximate D (3d) symmetry with crystallographically imposed inversion symmetry coincident with the bridging μ-O atom. The stereochemistry about each FeCl(3)O centre is distorted tetrahedral [Fe—Cl = 2.2176 (5)–2.2427 (5) Å and Fe—O = 1.7545 (2) Å]. The Cl atoms are involved in weak anion–cation C—H⋯Cl interactions, giving a network structure. |
| format | Text |
| id | pubmed-3006938 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30069382010-12-30 Bis(1,3-dibenzylimidazolium) μ-oxido-bis[trichloridoferrate(III)] Mutambi, E. M. Adams, C. J. Orpen, A. G. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound (C(17)H(17)N(2))(2)[Fe(2)Cl(6)O], obtained from the solid-state reaction of FeCl(2) and N,N′-dibenzylimidazolium chloride, the complex anion has approximate D (3d) symmetry with crystallographically imposed inversion symmetry coincident with the bridging μ-O atom. The stereochemistry about each FeCl(3)O centre is distorted tetrahedral [Fe—Cl = 2.2176 (5)–2.2427 (5) Å and Fe—O = 1.7545 (2) Å]. The Cl atoms are involved in weak anion–cation C—H⋯Cl interactions, giving a network structure. International Union of Crystallography 2010-06-26 /pmc/articles/PMC3006938/ /pubmed/21587757 http://dx.doi.org/10.1107/S1600536810024098 Text en © Mutambi et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Mutambi, E. M. Adams, C. J. Orpen, A. G. Bis(1,3-dibenzylimidazolium) μ-oxido-bis[trichloridoferrate(III)] |
| title | Bis(1,3-dibenzylimidazolium) μ-oxido-bis[trichloridoferrate(III)] |
| title_full | Bis(1,3-dibenzylimidazolium) μ-oxido-bis[trichloridoferrate(III)] |
| title_fullStr | Bis(1,3-dibenzylimidazolium) μ-oxido-bis[trichloridoferrate(III)] |
| title_full_unstemmed | Bis(1,3-dibenzylimidazolium) μ-oxido-bis[trichloridoferrate(III)] |
| title_short | Bis(1,3-dibenzylimidazolium) μ-oxido-bis[trichloridoferrate(III)] |
| title_sort | bis(1,3-dibenzylimidazolium) μ-oxido-bis[trichloridoferrate(iii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006938/ https://www.ncbi.nlm.nih.gov/pubmed/21587757 http://dx.doi.org/10.1107/S1600536810024098 |
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