trans-Tetra­kis(4-methyl­pyridine-κN)dioxidorhenium(V) hexa­fluorido­phosphate

The title compound, [ReO(2)(C(6)H(7)N)(4)]PF(6), contains octa­hedral [ReO(2)(4-Mepy)(4)](+) cations (4-Mepy is 4-methyl­pyridine) and PF(6) (−) anions. Both the cation and the anion reside on special positions, the Re atom on a crystallographic center of inversion and the P atom on a C (2) axis par...

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Detalles Bibliográficos
Autores principales: Kawasaki, Takeshi, Canlier, Ali, Chowdhury, Shubhamoy, Ikeda, Yasuhisa
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006941/
https://www.ncbi.nlm.nih.gov/pubmed/21587764
http://dx.doi.org/10.1107/S160053681002458X
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author Kawasaki, Takeshi
Canlier, Ali
Chowdhury, Shubhamoy
Ikeda, Yasuhisa
author_facet Kawasaki, Takeshi
Canlier, Ali
Chowdhury, Shubhamoy
Ikeda, Yasuhisa
author_sort Kawasaki, Takeshi
collection PubMed
description The title compound, [ReO(2)(C(6)H(7)N)(4)]PF(6), contains octa­hedral [ReO(2)(4-Mepy)(4)](+) cations (4-Mepy is 4-methyl­pyridine) and PF(6) (−) anions. Both the cation and the anion reside on special positions, the Re atom on a crystallographic center of inversion and the P atom on a C (2) axis parallel to the b axis. The Re(V) atom in the cation exhibits an octa­hedral coordination geometry with two O atoms in the apical positions and four N atoms of the 4-Mepy ligands in the equatorial plane. The Re=O and Re—N bond lengths fall in the typical ranges of trans-dioxidorhenium(V) complexes.
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spelling pubmed-30069412010-12-30 trans-Tetra­kis(4-methyl­pyridine-κN)dioxidorhenium(V) hexa­fluorido­phosphate Kawasaki, Takeshi Canlier, Ali Chowdhury, Shubhamoy Ikeda, Yasuhisa Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [ReO(2)(C(6)H(7)N)(4)]PF(6), contains octa­hedral [ReO(2)(4-Mepy)(4)](+) cations (4-Mepy is 4-methyl­pyridine) and PF(6) (−) anions. Both the cation and the anion reside on special positions, the Re atom on a crystallographic center of inversion and the P atom on a C (2) axis parallel to the b axis. The Re(V) atom in the cation exhibits an octa­hedral coordination geometry with two O atoms in the apical positions and four N atoms of the 4-Mepy ligands in the equatorial plane. The Re=O and Re—N bond lengths fall in the typical ranges of trans-dioxidorhenium(V) complexes. International Union of Crystallography 2010-06-26 /pmc/articles/PMC3006941/ /pubmed/21587764 http://dx.doi.org/10.1107/S160053681002458X Text en © Kawasaki et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kawasaki, Takeshi
Canlier, Ali
Chowdhury, Shubhamoy
Ikeda, Yasuhisa
trans-Tetra­kis(4-methyl­pyridine-κN)dioxidorhenium(V) hexa­fluorido­phosphate
title trans-Tetra­kis(4-methyl­pyridine-κN)dioxidorhenium(V) hexa­fluorido­phosphate
title_full trans-Tetra­kis(4-methyl­pyridine-κN)dioxidorhenium(V) hexa­fluorido­phosphate
title_fullStr trans-Tetra­kis(4-methyl­pyridine-κN)dioxidorhenium(V) hexa­fluorido­phosphate
title_full_unstemmed trans-Tetra­kis(4-methyl­pyridine-κN)dioxidorhenium(V) hexa­fluorido­phosphate
title_short trans-Tetra­kis(4-methyl­pyridine-κN)dioxidorhenium(V) hexa­fluorido­phosphate
title_sort trans-tetra­kis(4-methyl­pyridine-κn)dioxidorhenium(v) hexa­fluorido­phosphate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006941/
https://www.ncbi.nlm.nih.gov/pubmed/21587764
http://dx.doi.org/10.1107/S160053681002458X
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AT chowdhuryshubhamoy transtetrakis4methylpyridinekndioxidorheniumvhexafluoridophosphate
AT ikedayasuhisa transtetrakis4methylpyridinekndioxidorheniumvhexafluoridophosphate

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