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Tris(2,2′-bipyridine)cobalt(II) μ(6)-oxido-dodeca-μ(2)-oxido-hexaoxidohexamolydate(VI)
In the title compound, [Co(C(10)H(8)N(2))(3)][Mo(6)O(19)], the Co(2+) cation is surrounded in a distorted octahedral coordination by six N atoms from three 2,2′-bipyridine ligands. The distribution of Mo—O bond lengths in the Lindqvist isopolyanion is consistent with other structures containing the...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006945/ https://www.ncbi.nlm.nih.gov/pubmed/21587692 http://dx.doi.org/10.1107/S1600536810020775 |
| Sumario: | In the title compound, [Co(C(10)H(8)N(2))(3)][Mo(6)O(19)], the Co(2+) cation is surrounded in a distorted octahedral coordination by six N atoms from three 2,2′-bipyridine ligands. The distribution of Mo—O bond lengths in the Lindqvist isopolyanion is consistent with other structures containing the same unit. In the crystal, the cations and anions are linked by C—H⋯O interactions. |
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