Tris(2,2′-bipyridine)­cobalt(II) μ(6)-oxido-dodeca-μ(2)-oxido-hexa­oxidohexa­molydate(VI)

In the title compound, [Co(C(10)H(8)N(2))(3)][Mo(6)O(19)], the Co(2+) cation is surrounded in a distorted octa­hedral coordination by six N atoms from three 2,2′-bipyridine ligands. The distribution of Mo—O bond lengths in the Lindqvist isopolyanion is consistent with other structures containing the...

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Detalles Bibliográficos
Autores principales: Liu, Ying, Zhang, Xianxi, Xue, Zechun, Sheng, Jian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006945/
https://www.ncbi.nlm.nih.gov/pubmed/21587692
http://dx.doi.org/10.1107/S1600536810020775
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author Liu, Ying
Zhang, Xianxi
Xue, Zechun
Sheng, Jian
author_facet Liu, Ying
Zhang, Xianxi
Xue, Zechun
Sheng, Jian
author_sort Liu, Ying
collection PubMed
description In the title compound, [Co(C(10)H(8)N(2))(3)][Mo(6)O(19)], the Co(2+) cation is surrounded in a distorted octa­hedral coordination by six N atoms from three 2,2′-bipyridine ligands. The distribution of Mo—O bond lengths in the Lindqvist isopolyanion is consistent with other structures containing the same unit. In the crystal, the cations and anions are linked by C—H⋯O inter­actions.
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spelling pubmed-30069452010-12-30 Tris(2,2′-bipyridine)­cobalt(II) μ(6)-oxido-dodeca-μ(2)-oxido-hexa­oxidohexa­molydate(VI) Liu, Ying Zhang, Xianxi Xue, Zechun Sheng, Jian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(10)H(8)N(2))(3)][Mo(6)O(19)], the Co(2+) cation is surrounded in a distorted octa­hedral coordination by six N atoms from three 2,2′-bipyridine ligands. The distribution of Mo—O bond lengths in the Lindqvist isopolyanion is consistent with other structures containing the same unit. In the crystal, the cations and anions are linked by C—H⋯O inter­actions. International Union of Crystallography 2010-06-05 /pmc/articles/PMC3006945/ /pubmed/21587692 http://dx.doi.org/10.1107/S1600536810020775 Text en © Liu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Ying
Zhang, Xianxi
Xue, Zechun
Sheng, Jian
Tris(2,2′-bipyridine)­cobalt(II) μ(6)-oxido-dodeca-μ(2)-oxido-hexa­oxidohexa­molydate(VI)
title Tris(2,2′-bipyridine)­cobalt(II) μ(6)-oxido-dodeca-μ(2)-oxido-hexa­oxidohexa­molydate(VI)
title_full Tris(2,2′-bipyridine)­cobalt(II) μ(6)-oxido-dodeca-μ(2)-oxido-hexa­oxidohexa­molydate(VI)
title_fullStr Tris(2,2′-bipyridine)­cobalt(II) μ(6)-oxido-dodeca-μ(2)-oxido-hexa­oxidohexa­molydate(VI)
title_full_unstemmed Tris(2,2′-bipyridine)­cobalt(II) μ(6)-oxido-dodeca-μ(2)-oxido-hexa­oxidohexa­molydate(VI)
title_short Tris(2,2′-bipyridine)­cobalt(II) μ(6)-oxido-dodeca-μ(2)-oxido-hexa­oxidohexa­molydate(VI)
title_sort tris(2,2′-bipyridine)­cobalt(ii) μ(6)-oxido-dodeca-μ(2)-oxido-hexa­oxidohexa­molydate(vi)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006945/
https://www.ncbi.nlm.nih.gov/pubmed/21587692
http://dx.doi.org/10.1107/S1600536810020775
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