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(Z)-3-(2-{2-[1-(4-Hydroxyphenyl)ethylidene]hydrazin-1-yl}-1,3-thiazol-4-yl)-2H-chromen-2-one
In the title compound, C(20)H(15)N(3)O(3)S, an intramolecular C—H⋯O hydrogen bond generates an S(6) ring motif. The chromene ring system is inclined at dihedral angles of 14.21 (9) and 9.91 (10)°, respectively, with respect to the thiazole and benzene rings. The thiazole ring makes a dihedral ang...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006946/ https://www.ncbi.nlm.nih.gov/pubmed/21587863 http://dx.doi.org/10.1107/S1600536810021604 |
Sumario: | In the title compound, C(20)H(15)N(3)O(3)S, an intramolecular C—H⋯O hydrogen bond generates an S(6) ring motif. The chromene ring system is inclined at dihedral angles of 14.21 (9) and 9.91 (10)°, respectively, with respect to the thiazole and benzene rings. The thiazole ring makes a dihedral angle of 24.06 (11)° with the benzene ring. In the crystal structure, O—H⋯O hydrogen bonds link the molecules into a zigzag chain along [20[Image: see text]]. Weak N—H⋯O and C—H⋯O interactions connect the chains into a three-dimensional network. π–π stacking interactions with a centroid–centroid distance of 3.4209 (14) Å are also observed between the chains. |
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