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(Z)-3-(2-{2-[1-(4-Hydroxyphenyl)ethylidene]hydrazin-1-yl}-1,3-thiazol-4-yl)-2H-chromen-2-one
In the title compound, C(20)H(15)N(3)O(3)S, an intramolecular C—H⋯O hydrogen bond generates an S(6) ring motif. The chromene ring system is inclined at dihedral angles of 14.21 (9) and 9.91 (10)°, respectively, with respect to the thiazole and benzene rings. The thiazole ring makes a dihedral ang...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006946/ https://www.ncbi.nlm.nih.gov/pubmed/21587863 http://dx.doi.org/10.1107/S1600536810021604 |
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author | Arshad, Afsheen Osman, Hasnah Lam, Chan Kit Quah, Ching Kheng Fun, Hoong-Kun |
author_facet | Arshad, Afsheen Osman, Hasnah Lam, Chan Kit Quah, Ching Kheng Fun, Hoong-Kun |
author_sort | Arshad, Afsheen |
collection | PubMed |
description | In the title compound, C(20)H(15)N(3)O(3)S, an intramolecular C—H⋯O hydrogen bond generates an S(6) ring motif. The chromene ring system is inclined at dihedral angles of 14.21 (9) and 9.91 (10)°, respectively, with respect to the thiazole and benzene rings. The thiazole ring makes a dihedral angle of 24.06 (11)° with the benzene ring. In the crystal structure, O—H⋯O hydrogen bonds link the molecules into a zigzag chain along [20[Image: see text]]. Weak N—H⋯O and C—H⋯O interactions connect the chains into a three-dimensional network. π–π stacking interactions with a centroid–centroid distance of 3.4209 (14) Å are also observed between the chains. |
format | Text |
id | pubmed-3006946 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30069462010-12-30 (Z)-3-(2-{2-[1-(4-Hydroxyphenyl)ethylidene]hydrazin-1-yl}-1,3-thiazol-4-yl)-2H-chromen-2-one Arshad, Afsheen Osman, Hasnah Lam, Chan Kit Quah, Ching Kheng Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(20)H(15)N(3)O(3)S, an intramolecular C—H⋯O hydrogen bond generates an S(6) ring motif. The chromene ring system is inclined at dihedral angles of 14.21 (9) and 9.91 (10)°, respectively, with respect to the thiazole and benzene rings. The thiazole ring makes a dihedral angle of 24.06 (11)° with the benzene ring. In the crystal structure, O—H⋯O hydrogen bonds link the molecules into a zigzag chain along [20[Image: see text]]. Weak N—H⋯O and C—H⋯O interactions connect the chains into a three-dimensional network. π–π stacking interactions with a centroid–centroid distance of 3.4209 (14) Å are also observed between the chains. International Union of Crystallography 2010-06-16 /pmc/articles/PMC3006946/ /pubmed/21587863 http://dx.doi.org/10.1107/S1600536810021604 Text en © Arshad et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Arshad, Afsheen Osman, Hasnah Lam, Chan Kit Quah, Ching Kheng Fun, Hoong-Kun (Z)-3-(2-{2-[1-(4-Hydroxyphenyl)ethylidene]hydrazin-1-yl}-1,3-thiazol-4-yl)-2H-chromen-2-one |
title | (Z)-3-(2-{2-[1-(4-Hydroxyphenyl)ethylidene]hydrazin-1-yl}-1,3-thiazol-4-yl)-2H-chromen-2-one |
title_full | (Z)-3-(2-{2-[1-(4-Hydroxyphenyl)ethylidene]hydrazin-1-yl}-1,3-thiazol-4-yl)-2H-chromen-2-one |
title_fullStr | (Z)-3-(2-{2-[1-(4-Hydroxyphenyl)ethylidene]hydrazin-1-yl}-1,3-thiazol-4-yl)-2H-chromen-2-one |
title_full_unstemmed | (Z)-3-(2-{2-[1-(4-Hydroxyphenyl)ethylidene]hydrazin-1-yl}-1,3-thiazol-4-yl)-2H-chromen-2-one |
title_short | (Z)-3-(2-{2-[1-(4-Hydroxyphenyl)ethylidene]hydrazin-1-yl}-1,3-thiazol-4-yl)-2H-chromen-2-one |
title_sort | (z)-3-(2-{2-[1-(4-hydroxyphenyl)ethylidene]hydrazin-1-yl}-1,3-thiazol-4-yl)-2h-chromen-2-one |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006946/ https://www.ncbi.nlm.nih.gov/pubmed/21587863 http://dx.doi.org/10.1107/S1600536810021604 |
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