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(Z)-3-(2-{2-[1-(4-Hy­droxy­phen­yl)ethyl­idene]hydrazin-1-yl}-1,3-thia­zol-4-yl)-2H-chromen-2-one

In the title compound, C(20)H(15)N(3)O(3)S, an intra­molecular C—H⋯O hydrogen bond generates an S(6) ring motif. The chromene ring system is inclined at dihedral angles of 14.21 (9) and 9.91 (10)°, respectively, with respect to the thia­zole and benzene rings. The thia­zole ring makes a dihedral ang...

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Autores principales: Arshad, Afsheen, Osman, Hasnah, Lam, Chan Kit, Quah, Ching Kheng, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006946/
https://www.ncbi.nlm.nih.gov/pubmed/21587863
http://dx.doi.org/10.1107/S1600536810021604
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author Arshad, Afsheen
Osman, Hasnah
Lam, Chan Kit
Quah, Ching Kheng
Fun, Hoong-Kun
author_facet Arshad, Afsheen
Osman, Hasnah
Lam, Chan Kit
Quah, Ching Kheng
Fun, Hoong-Kun
author_sort Arshad, Afsheen
collection PubMed
description In the title compound, C(20)H(15)N(3)O(3)S, an intra­molecular C—H⋯O hydrogen bond generates an S(6) ring motif. The chromene ring system is inclined at dihedral angles of 14.21 (9) and 9.91 (10)°, respectively, with respect to the thia­zole and benzene rings. The thia­zole ring makes a dihedral angle of 24.06 (11)° with the benzene ring. In the crystal structure, O—H⋯O hydrogen bonds link the mol­ecules into a zigzag chain along [20[Image: see text]]. Weak N—H⋯O and C—H⋯O inter­actions connect the chains into a three-dimensional network. π–π stacking inter­actions with a centroid–centroid distance of 3.4209 (14) Å are also observed between the chains.
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spelling pubmed-30069462010-12-30 (Z)-3-(2-{2-[1-(4-Hy­droxy­phen­yl)ethyl­idene]hydrazin-1-yl}-1,3-thia­zol-4-yl)-2H-chromen-2-one Arshad, Afsheen Osman, Hasnah Lam, Chan Kit Quah, Ching Kheng Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(20)H(15)N(3)O(3)S, an intra­molecular C—H⋯O hydrogen bond generates an S(6) ring motif. The chromene ring system is inclined at dihedral angles of 14.21 (9) and 9.91 (10)°, respectively, with respect to the thia­zole and benzene rings. The thia­zole ring makes a dihedral angle of 24.06 (11)° with the benzene ring. In the crystal structure, O—H⋯O hydrogen bonds link the mol­ecules into a zigzag chain along [20[Image: see text]]. Weak N—H⋯O and C—H⋯O inter­actions connect the chains into a three-dimensional network. π–π stacking inter­actions with a centroid–centroid distance of 3.4209 (14) Å are also observed between the chains. International Union of Crystallography 2010-06-16 /pmc/articles/PMC3006946/ /pubmed/21587863 http://dx.doi.org/10.1107/S1600536810021604 Text en © Arshad et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Arshad, Afsheen
Osman, Hasnah
Lam, Chan Kit
Quah, Ching Kheng
Fun, Hoong-Kun
(Z)-3-(2-{2-[1-(4-Hy­droxy­phen­yl)ethyl­idene]hydrazin-1-yl}-1,3-thia­zol-4-yl)-2H-chromen-2-one
title (Z)-3-(2-{2-[1-(4-Hy­droxy­phen­yl)ethyl­idene]hydrazin-1-yl}-1,3-thia­zol-4-yl)-2H-chromen-2-one
title_full (Z)-3-(2-{2-[1-(4-Hy­droxy­phen­yl)ethyl­idene]hydrazin-1-yl}-1,3-thia­zol-4-yl)-2H-chromen-2-one
title_fullStr (Z)-3-(2-{2-[1-(4-Hy­droxy­phen­yl)ethyl­idene]hydrazin-1-yl}-1,3-thia­zol-4-yl)-2H-chromen-2-one
title_full_unstemmed (Z)-3-(2-{2-[1-(4-Hy­droxy­phen­yl)ethyl­idene]hydrazin-1-yl}-1,3-thia­zol-4-yl)-2H-chromen-2-one
title_short (Z)-3-(2-{2-[1-(4-Hy­droxy­phen­yl)ethyl­idene]hydrazin-1-yl}-1,3-thia­zol-4-yl)-2H-chromen-2-one
title_sort (z)-3-(2-{2-[1-(4-hy­droxy­phen­yl)ethyl­idene]hydrazin-1-yl}-1,3-thia­zol-4-yl)-2h-chromen-2-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006946/
https://www.ncbi.nlm.nih.gov/pubmed/21587863
http://dx.doi.org/10.1107/S1600536810021604
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