(Acetyl­acetonato-κ(2) O,O′)chlorido­trimethano­latoniobium(V)

In the title compound, [Nb(CH(3)O)(3)(C(5)H(7)O(2))Cl], the Nb(V) atom is coordinated by two O atoms from the chelating acetyl­acetonate ligand, three O atoms from the methano­late groups and one chloride ligand. The octa­hedral environment around niobium is slightly distorted with Nb—O distances in...

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Detalles Bibliográficos
Autores principales: Herbst, Leandra, Koen, Renier, Roodt, Andreas, Visser, Hendrik G.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006950/
https://www.ncbi.nlm.nih.gov/pubmed/21587722
http://dx.doi.org/10.1107/S1600536810021719
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author Herbst, Leandra
Koen, Renier
Roodt, Andreas
Visser, Hendrik G.
author_facet Herbst, Leandra
Koen, Renier
Roodt, Andreas
Visser, Hendrik G.
author_sort Herbst, Leandra
collection PubMed
description In the title compound, [Nb(CH(3)O)(3)(C(5)H(7)O(2))Cl], the Nb(V) atom is coordinated by two O atoms from the chelating acetyl­acetonate ligand, three O atoms from the methano­late groups and one chloride ligand. The octa­hedral environment around niobium is slightly distorted with Nb—O distances in the range 1.8603 (15)–2.1083 (15) Å and an Nb—Cl distance of 2.4693 (9) Å. The O—Nb—O angles vary between 80.74 (6) and 100.82 (7)°, while the trans Cl—Nb—O angle is 167.60 (5)°. There are no hydrogen bonds observed, only an inter­molecular C—H⋯O inter­action.
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spelling pubmed-30069502010-12-30 (Acetyl­acetonato-κ(2) O,O′)chlorido­trimethano­latoniobium(V) Herbst, Leandra Koen, Renier Roodt, Andreas Visser, Hendrik G. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Nb(CH(3)O)(3)(C(5)H(7)O(2))Cl], the Nb(V) atom is coordinated by two O atoms from the chelating acetyl­acetonate ligand, three O atoms from the methano­late groups and one chloride ligand. The octa­hedral environment around niobium is slightly distorted with Nb—O distances in the range 1.8603 (15)–2.1083 (15) Å and an Nb—Cl distance of 2.4693 (9) Å. The O—Nb—O angles vary between 80.74 (6) and 100.82 (7)°, while the trans Cl—Nb—O angle is 167.60 (5)°. There are no hydrogen bonds observed, only an inter­molecular C—H⋯O inter­action. International Union of Crystallography 2010-06-16 /pmc/articles/PMC3006950/ /pubmed/21587722 http://dx.doi.org/10.1107/S1600536810021719 Text en © Herbst et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Herbst, Leandra
Koen, Renier
Roodt, Andreas
Visser, Hendrik G.
(Acetyl­acetonato-κ(2) O,O′)chlorido­trimethano­latoniobium(V)
title (Acetyl­acetonato-κ(2) O,O′)chlorido­trimethano­latoniobium(V)
title_full (Acetyl­acetonato-κ(2) O,O′)chlorido­trimethano­latoniobium(V)
title_fullStr (Acetyl­acetonato-κ(2) O,O′)chlorido­trimethano­latoniobium(V)
title_full_unstemmed (Acetyl­acetonato-κ(2) O,O′)chlorido­trimethano­latoniobium(V)
title_short (Acetyl­acetonato-κ(2) O,O′)chlorido­trimethano­latoniobium(V)
title_sort (acetyl­acetonato-κ(2) o,o′)chlorido­trimethano­latoniobium(v)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006950/
https://www.ncbi.nlm.nih.gov/pubmed/21587722
http://dx.doi.org/10.1107/S1600536810021719
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AT koenrenier acetylacetonatok2oochloridotrimethanolatoniobiumv
AT roodtandreas acetylacetonatok2oochloridotrimethanolatoniobiumv
AT visserhendrikg acetylacetonatok2oochloridotrimethanolatoniobiumv

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