[5,10,15,20-Tetra­kis(4-tol­yl)porphyrin]zinc(II) dichloro­methane solvate

In the title complex, [Zn(C(48)H(36)N(4))]·CH(2)Cl(2), the Zn(II) atom lies on an inversion center and the dichloro­methane solvent mol­ecule is disordered around an inversion center. The tolyl substituents are twisted compared to the central aromatic ring system of the porphyrin, similar to what is...

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Detalles Bibliográficos
Autores principales: McGill, Sean, Nesterov, Vladimir N., Gould, Stephanie L.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006952/
https://www.ncbi.nlm.nih.gov/pubmed/21587669
http://dx.doi.org/10.1107/S1600536810019963
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author McGill, Sean
Nesterov, Vladimir N.
Gould, Stephanie L.
author_facet McGill, Sean
Nesterov, Vladimir N.
Gould, Stephanie L.
author_sort McGill, Sean
collection PubMed
description In the title complex, [Zn(C(48)H(36)N(4))]·CH(2)Cl(2), the Zn(II) atom lies on an inversion center and the dichloro­methane solvent mol­ecule is disordered around an inversion center. The tolyl substituents are twisted compared to the central aromatic ring system of the porphyrin, similar to what is seen in previously published structures of this molecule [Dastidar & Goldberg (1996 ▶). Acta Cryst. C52, 1976–1980]. The dihedral angles between the mean planes of the tolyl rings and the central ring are 66.98 (6) and 60.40 (6)°.
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spelling pubmed-30069522010-12-30 [5,10,15,20-Tetra­kis(4-tol­yl)porphyrin]zinc(II) dichloro­methane solvate McGill, Sean Nesterov, Vladimir N. Gould, Stephanie L. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Zn(C(48)H(36)N(4))]·CH(2)Cl(2), the Zn(II) atom lies on an inversion center and the dichloro­methane solvent mol­ecule is disordered around an inversion center. The tolyl substituents are twisted compared to the central aromatic ring system of the porphyrin, similar to what is seen in previously published structures of this molecule [Dastidar & Goldberg (1996 ▶). Acta Cryst. C52, 1976–1980]. The dihedral angles between the mean planes of the tolyl rings and the central ring are 66.98 (6) and 60.40 (6)°. International Union of Crystallography 2010-06-05 /pmc/articles/PMC3006952/ /pubmed/21587669 http://dx.doi.org/10.1107/S1600536810019963 Text en © McGill et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
McGill, Sean
Nesterov, Vladimir N.
Gould, Stephanie L.
[5,10,15,20-Tetra­kis(4-tol­yl)porphyrin]zinc(II) dichloro­methane solvate
title [5,10,15,20-Tetra­kis(4-tol­yl)porphyrin]zinc(II) dichloro­methane solvate
title_full [5,10,15,20-Tetra­kis(4-tol­yl)porphyrin]zinc(II) dichloro­methane solvate
title_fullStr [5,10,15,20-Tetra­kis(4-tol­yl)porphyrin]zinc(II) dichloro­methane solvate
title_full_unstemmed [5,10,15,20-Tetra­kis(4-tol­yl)porphyrin]zinc(II) dichloro­methane solvate
title_short [5,10,15,20-Tetra­kis(4-tol­yl)porphyrin]zinc(II) dichloro­methane solvate
title_sort [5,10,15,20-tetra­kis(4-tol­yl)porphyrin]zinc(ii) dichloro­methane solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006952/
https://www.ncbi.nlm.nih.gov/pubmed/21587669
http://dx.doi.org/10.1107/S1600536810019963
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AT gouldstephaniel 5101520tetrakis4tolylporphyrinzinciidichloromethanesolvate

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