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Tetracarbonyl-1κ(2) C,3κ(2) C-bis[1,3(η(5))-cyclopentadienyl]dihydroxido-2κ(2) O-diirontin(2 Fe—Sn) monohydrate
In the title hydrate, [Fe(2)Sn(C(5)H(5))(2)(OH)(2)(CO)(4)]·H(2)O, the central Sn atom is tetrahedrally coordinated by two {Cp(CO)(2)Fe} fragments and two hydroxide groups. The [{Cp(CO)(2)Fe}(2)Sn(OH)(2)] and water molecules are linked by O—H⋯O hydrogen bridges, giving two-dimensional arrays with 4...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006954/ https://www.ncbi.nlm.nih.gov/pubmed/21587729 http://dx.doi.org/10.1107/S1600536810021975 |
| _version_ | 1782194262693117952 |
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| author | Kössel, Stefanie Wagner, Christoph Merzweiler, Kurt |
| author_facet | Kössel, Stefanie Wagner, Christoph Merzweiler, Kurt |
| author_sort | Kössel, Stefanie |
| collection | PubMed |
| description | In the title hydrate, [Fe(2)Sn(C(5)H(5))(2)(OH)(2)(CO)(4)]·H(2)O, the central Sn atom is tetrahedrally coordinated by two {Cp(CO)(2)Fe} fragments and two hydroxide groups. The [{Cp(CO)(2)Fe}(2)Sn(OH)(2)] and water molecules are linked by O—H⋯O hydrogen bridges, giving two-dimensional arrays with 4.8(2) topology that stack along the c axis. |
| format | Text |
| id | pubmed-3006954 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30069542010-12-30 Tetracarbonyl-1κ(2) C,3κ(2) C-bis[1,3(η(5))-cyclopentadienyl]dihydroxido-2κ(2) O-diirontin(2 Fe—Sn) monohydrate Kössel, Stefanie Wagner, Christoph Merzweiler, Kurt Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title hydrate, [Fe(2)Sn(C(5)H(5))(2)(OH)(2)(CO)(4)]·H(2)O, the central Sn atom is tetrahedrally coordinated by two {Cp(CO)(2)Fe} fragments and two hydroxide groups. The [{Cp(CO)(2)Fe}(2)Sn(OH)(2)] and water molecules are linked by O—H⋯O hydrogen bridges, giving two-dimensional arrays with 4.8(2) topology that stack along the c axis. International Union of Crystallography 2010-06-18 /pmc/articles/PMC3006954/ /pubmed/21587729 http://dx.doi.org/10.1107/S1600536810021975 Text en © Kössel et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Kössel, Stefanie Wagner, Christoph Merzweiler, Kurt Tetracarbonyl-1κ(2) C,3κ(2) C-bis[1,3(η(5))-cyclopentadienyl]dihydroxido-2κ(2) O-diirontin(2 Fe—Sn) monohydrate |
| title | Tetracarbonyl-1κ(2)
C,3κ(2)
C-bis[1,3(η(5))-cyclopentadienyl]dihydroxido-2κ(2)
O-diirontin(2 Fe—Sn) monohydrate |
| title_full | Tetracarbonyl-1κ(2)
C,3κ(2)
C-bis[1,3(η(5))-cyclopentadienyl]dihydroxido-2κ(2)
O-diirontin(2 Fe—Sn) monohydrate |
| title_fullStr | Tetracarbonyl-1κ(2)
C,3κ(2)
C-bis[1,3(η(5))-cyclopentadienyl]dihydroxido-2κ(2)
O-diirontin(2 Fe—Sn) monohydrate |
| title_full_unstemmed | Tetracarbonyl-1κ(2)
C,3κ(2)
C-bis[1,3(η(5))-cyclopentadienyl]dihydroxido-2κ(2)
O-diirontin(2 Fe—Sn) monohydrate |
| title_short | Tetracarbonyl-1κ(2)
C,3κ(2)
C-bis[1,3(η(5))-cyclopentadienyl]dihydroxido-2κ(2)
O-diirontin(2 Fe—Sn) monohydrate |
| title_sort | tetracarbonyl-1κ(2)
c,3κ(2)
c-bis[1,3(η(5))-cyclopentadienyl]dihydroxido-2κ(2)
o-diirontin(2 fe—sn) monohydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006954/ https://www.ncbi.nlm.nih.gov/pubmed/21587729 http://dx.doi.org/10.1107/S1600536810021975 |
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