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1-Cyanomethyl-1,4-diazoniabicyclo[2.2.2]octane tetrabromidocuprate(II)
In the crystal structure of the title complex, (C(8)H(15)N(3))[CuBr(4)], the Cu atom is coordinated by four bromido ligands within a strongly distorted tetrahedron. The anions and cations are connected by weak N—H⋯Br and C—H⋯Br hydrogen-bonding interactions.
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006955/ https://www.ncbi.nlm.nih.gov/pubmed/21587743 http://dx.doi.org/10.1107/S1600536810023469 |
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author | Cai, Ying |
author_facet | Cai, Ying |
author_sort | Cai, Ying |
collection | PubMed |
description | In the crystal structure of the title complex, (C(8)H(15)N(3))[CuBr(4)], the Cu atom is coordinated by four bromido ligands within a strongly distorted tetrahedron. The anions and cations are connected by weak N—H⋯Br and C—H⋯Br hydrogen-bonding interactions. |
format | Text |
id | pubmed-3006955 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30069552010-12-30 1-Cyanomethyl-1,4-diazoniabicyclo[2.2.2]octane tetrabromidocuprate(II) Cai, Ying Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title complex, (C(8)H(15)N(3))[CuBr(4)], the Cu atom is coordinated by four bromido ligands within a strongly distorted tetrahedron. The anions and cations are connected by weak N—H⋯Br and C—H⋯Br hydrogen-bonding interactions. International Union of Crystallography 2010-06-23 /pmc/articles/PMC3006955/ /pubmed/21587743 http://dx.doi.org/10.1107/S1600536810023469 Text en © Ying Cai 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Cai, Ying 1-Cyanomethyl-1,4-diazoniabicyclo[2.2.2]octane tetrabromidocuprate(II) |
title | 1-Cyanomethyl-1,4-diazoniabicyclo[2.2.2]octane tetrabromidocuprate(II) |
title_full | 1-Cyanomethyl-1,4-diazoniabicyclo[2.2.2]octane tetrabromidocuprate(II) |
title_fullStr | 1-Cyanomethyl-1,4-diazoniabicyclo[2.2.2]octane tetrabromidocuprate(II) |
title_full_unstemmed | 1-Cyanomethyl-1,4-diazoniabicyclo[2.2.2]octane tetrabromidocuprate(II) |
title_short | 1-Cyanomethyl-1,4-diazoniabicyclo[2.2.2]octane tetrabromidocuprate(II) |
title_sort | 1-cyanomethyl-1,4-diazoniabicyclo[2.2.2]octane tetrabromidocuprate(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006955/ https://www.ncbi.nlm.nih.gov/pubmed/21587743 http://dx.doi.org/10.1107/S1600536810023469 |
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