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2,3-Dimethyl-6-nitro­quinoxaline

The asymmetric unit of the title quinoxaline compound, C(10)H(9)N(3)O(2), contains two crystallographically independent mol­ecules (A and B). The quinoxaline ring systems are essentially planar, with maximum deviations of 0.006 (1) and 0.017 (1) Å, respectively, for mol­ecules A and B. In mol­ecule...

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Detalles Bibliográficos
Autores principales: Ghalib, Raza Murad, Hashim, Rokiah, Mehdi, Sayed Hasan, Goh, Jia Hao, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006956/
https://www.ncbi.nlm.nih.gov/pubmed/21588035
http://dx.doi.org/10.1107/S1600536810024463
Descripción
Sumario:The asymmetric unit of the title quinoxaline compound, C(10)H(9)N(3)O(2), contains two crystallographically independent mol­ecules (A and B). The quinoxaline ring systems are essentially planar, with maximum deviations of 0.006 (1) and 0.017 (1) Å, respectively, for mol­ecules A and B. In mol­ecule A, the dihedral angle formed between the quinoxaline ring system and nitro group is 10.94 (3)° [6.31 (13)° for mol­ecule B]. In the crystal, mol­ecules are linked into chains propagating along [001]: one forms zigzag chains linked by C—H⋯O hydrogen bonds, whilst the other forms ladder-like chains by way of C—H⋯N and C—H⋯O hydrogen bonds. The packing is further consolidated by weak π–π inter­actions [range of centroid–centroid distances = 3.5895 (7)–3.6324 (7) Å].