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2,3-Dimethyl-6-nitroquinoxaline
The asymmetric unit of the title quinoxaline compound, C(10)H(9)N(3)O(2), contains two crystallographically independent molecules (A and B). The quinoxaline ring systems are essentially planar, with maximum deviations of 0.006 (1) and 0.017 (1) Å, respectively, for molecules A and B. In molecule...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006956/ https://www.ncbi.nlm.nih.gov/pubmed/21588035 http://dx.doi.org/10.1107/S1600536810024463 |
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author | Ghalib, Raza Murad Hashim, Rokiah Mehdi, Sayed Hasan Goh, Jia Hao Fun, Hoong-Kun |
author_facet | Ghalib, Raza Murad Hashim, Rokiah Mehdi, Sayed Hasan Goh, Jia Hao Fun, Hoong-Kun |
author_sort | Ghalib, Raza Murad |
collection | PubMed |
description | The asymmetric unit of the title quinoxaline compound, C(10)H(9)N(3)O(2), contains two crystallographically independent molecules (A and B). The quinoxaline ring systems are essentially planar, with maximum deviations of 0.006 (1) and 0.017 (1) Å, respectively, for molecules A and B. In molecule A, the dihedral angle formed between the quinoxaline ring system and nitro group is 10.94 (3)° [6.31 (13)° for molecule B]. In the crystal, molecules are linked into chains propagating along [001]: one forms zigzag chains linked by C—H⋯O hydrogen bonds, whilst the other forms ladder-like chains by way of C—H⋯N and C—H⋯O hydrogen bonds. The packing is further consolidated by weak π–π interactions [range of centroid–centroid distances = 3.5895 (7)–3.6324 (7) Å]. |
format | Text |
id | pubmed-3006956 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30069562010-12-30 2,3-Dimethyl-6-nitroquinoxaline Ghalib, Raza Murad Hashim, Rokiah Mehdi, Sayed Hasan Goh, Jia Hao Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title quinoxaline compound, C(10)H(9)N(3)O(2), contains two crystallographically independent molecules (A and B). The quinoxaline ring systems are essentially planar, with maximum deviations of 0.006 (1) and 0.017 (1) Å, respectively, for molecules A and B. In molecule A, the dihedral angle formed between the quinoxaline ring system and nitro group is 10.94 (3)° [6.31 (13)° for molecule B]. In the crystal, molecules are linked into chains propagating along [001]: one forms zigzag chains linked by C—H⋯O hydrogen bonds, whilst the other forms ladder-like chains by way of C—H⋯N and C—H⋯O hydrogen bonds. The packing is further consolidated by weak π–π interactions [range of centroid–centroid distances = 3.5895 (7)–3.6324 (7) Å]. International Union of Crystallography 2010-06-26 /pmc/articles/PMC3006956/ /pubmed/21588035 http://dx.doi.org/10.1107/S1600536810024463 Text en © Ghalib et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Ghalib, Raza Murad Hashim, Rokiah Mehdi, Sayed Hasan Goh, Jia Hao Fun, Hoong-Kun 2,3-Dimethyl-6-nitroquinoxaline |
title | 2,3-Dimethyl-6-nitroquinoxaline |
title_full | 2,3-Dimethyl-6-nitroquinoxaline |
title_fullStr | 2,3-Dimethyl-6-nitroquinoxaline |
title_full_unstemmed | 2,3-Dimethyl-6-nitroquinoxaline |
title_short | 2,3-Dimethyl-6-nitroquinoxaline |
title_sort | 2,3-dimethyl-6-nitroquinoxaline |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006956/ https://www.ncbi.nlm.nih.gov/pubmed/21588035 http://dx.doi.org/10.1107/S1600536810024463 |
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