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2,3-Dimethyl-6-nitro­quinoxaline

The asymmetric unit of the title quinoxaline compound, C(10)H(9)N(3)O(2), contains two crystallographically independent mol­ecules (A and B). The quinoxaline ring systems are essentially planar, with maximum deviations of 0.006 (1) and 0.017 (1) Å, respectively, for mol­ecules A and B. In mol­ecule...

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Autores principales: Ghalib, Raza Murad, Hashim, Rokiah, Mehdi, Sayed Hasan, Goh, Jia Hao, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006956/
https://www.ncbi.nlm.nih.gov/pubmed/21588035
http://dx.doi.org/10.1107/S1600536810024463
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author Ghalib, Raza Murad
Hashim, Rokiah
Mehdi, Sayed Hasan
Goh, Jia Hao
Fun, Hoong-Kun
author_facet Ghalib, Raza Murad
Hashim, Rokiah
Mehdi, Sayed Hasan
Goh, Jia Hao
Fun, Hoong-Kun
author_sort Ghalib, Raza Murad
collection PubMed
description The asymmetric unit of the title quinoxaline compound, C(10)H(9)N(3)O(2), contains two crystallographically independent mol­ecules (A and B). The quinoxaline ring systems are essentially planar, with maximum deviations of 0.006 (1) and 0.017 (1) Å, respectively, for mol­ecules A and B. In mol­ecule A, the dihedral angle formed between the quinoxaline ring system and nitro group is 10.94 (3)° [6.31 (13)° for mol­ecule B]. In the crystal, mol­ecules are linked into chains propagating along [001]: one forms zigzag chains linked by C—H⋯O hydrogen bonds, whilst the other forms ladder-like chains by way of C—H⋯N and C—H⋯O hydrogen bonds. The packing is further consolidated by weak π–π inter­actions [range of centroid–centroid distances = 3.5895 (7)–3.6324 (7) Å].
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spelling pubmed-30069562010-12-30 2,3-Dimethyl-6-nitro­quinoxaline Ghalib, Raza Murad Hashim, Rokiah Mehdi, Sayed Hasan Goh, Jia Hao Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title quinoxaline compound, C(10)H(9)N(3)O(2), contains two crystallographically independent mol­ecules (A and B). The quinoxaline ring systems are essentially planar, with maximum deviations of 0.006 (1) and 0.017 (1) Å, respectively, for mol­ecules A and B. In mol­ecule A, the dihedral angle formed between the quinoxaline ring system and nitro group is 10.94 (3)° [6.31 (13)° for mol­ecule B]. In the crystal, mol­ecules are linked into chains propagating along [001]: one forms zigzag chains linked by C—H⋯O hydrogen bonds, whilst the other forms ladder-like chains by way of C—H⋯N and C—H⋯O hydrogen bonds. The packing is further consolidated by weak π–π inter­actions [range of centroid–centroid distances = 3.5895 (7)–3.6324 (7) Å]. International Union of Crystallography 2010-06-26 /pmc/articles/PMC3006956/ /pubmed/21588035 http://dx.doi.org/10.1107/S1600536810024463 Text en © Ghalib et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ghalib, Raza Murad
Hashim, Rokiah
Mehdi, Sayed Hasan
Goh, Jia Hao
Fun, Hoong-Kun
2,3-Dimethyl-6-nitro­quinoxaline
title 2,3-Dimethyl-6-nitro­quinoxaline
title_full 2,3-Dimethyl-6-nitro­quinoxaline
title_fullStr 2,3-Dimethyl-6-nitro­quinoxaline
title_full_unstemmed 2,3-Dimethyl-6-nitro­quinoxaline
title_short 2,3-Dimethyl-6-nitro­quinoxaline
title_sort 2,3-dimethyl-6-nitro­quinoxaline
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006956/
https://www.ncbi.nlm.nih.gov/pubmed/21588035
http://dx.doi.org/10.1107/S1600536810024463
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