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N-(3-Chlorophenyl)maleamic acid
In the title compound, C(10)H(8)ClNO(3), the molecular conformation is stabilized by two intramolecular hydrogen bonds. The first is a short O—H⋯O hydrogen bond within the maleamic acid unit and the second is a C—H⋯O hydrogen bond which connects the amide group with the phenyl ring. The maleamic ac...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006958/ https://www.ncbi.nlm.nih.gov/pubmed/21587872 http://dx.doi.org/10.1107/S1600536810021446 |
Sumario: | In the title compound, C(10)H(8)ClNO(3), the molecular conformation is stabilized by two intramolecular hydrogen bonds. The first is a short O—H⋯O hydrogen bond within the maleamic acid unit and the second is a C—H⋯O hydrogen bond which connects the amide group with the phenyl ring. The maleamic acid unit is essentially planar, with an r.m.s. deviation of 0.044 Å, and makes a dihedral angle of 15.2 (1)° with the phenyl ring. In the crystal, intermolecular N—H⋯O hydrogen bonds link the molecules into C(7) chains running [010]. |
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