N-(3-Chloro­phen­yl)maleamic acid

In the title compound, C(10)H(8)ClNO(3), the molecular conformation is stabilized by two intra­molecular hydrogen bonds. The first is a short O—H⋯O hydrogen bond within the maleamic acid unit and the second is a C—H⋯O hydrogen bond which connects the amide group with the phenyl ring. The maleamic ac...

Descripción completa

Detalles Bibliográficos
Autores principales: Gowda, B. Thimme, Tokarčík, Miroslav, Shakuntala, K., Kožíšek, Jozef, Fuess, Hartmut
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006958/
https://www.ncbi.nlm.nih.gov/pubmed/21587872
http://dx.doi.org/10.1107/S1600536810021446
_version_ 1782194263646273536
author Gowda, B. Thimme
Tokarčík, Miroslav
Shakuntala, K.
Kožíšek, Jozef
Fuess, Hartmut
author_facet Gowda, B. Thimme
Tokarčík, Miroslav
Shakuntala, K.
Kožíšek, Jozef
Fuess, Hartmut
author_sort Gowda, B. Thimme
collection PubMed
description In the title compound, C(10)H(8)ClNO(3), the molecular conformation is stabilized by two intra­molecular hydrogen bonds. The first is a short O—H⋯O hydrogen bond within the maleamic acid unit and the second is a C—H⋯O hydrogen bond which connects the amide group with the phenyl ring. The maleamic acid unit is essentially planar, with an r.m.s. deviation of 0.044 Å, and makes a dihedral angle of 15.2 (1)° with the phenyl ring. In the crystal, inter­molecular N—H⋯O hydrogen bonds link the mol­ecules into C(7) chains running [010].
format Text
id pubmed-3006958
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30069582010-12-30 N-(3-Chloro­phen­yl)maleamic acid Gowda, B. Thimme Tokarčík, Miroslav Shakuntala, K. Kožíšek, Jozef Fuess, Hartmut Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(10)H(8)ClNO(3), the molecular conformation is stabilized by two intra­molecular hydrogen bonds. The first is a short O—H⋯O hydrogen bond within the maleamic acid unit and the second is a C—H⋯O hydrogen bond which connects the amide group with the phenyl ring. The maleamic acid unit is essentially planar, with an r.m.s. deviation of 0.044 Å, and makes a dihedral angle of 15.2 (1)° with the phenyl ring. In the crystal, inter­molecular N—H⋯O hydrogen bonds link the mol­ecules into C(7) chains running [010]. International Union of Crystallography 2010-06-16 /pmc/articles/PMC3006958/ /pubmed/21587872 http://dx.doi.org/10.1107/S1600536810021446 Text en © Gowda et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gowda, B. Thimme
Tokarčík, Miroslav
Shakuntala, K.
Kožíšek, Jozef
Fuess, Hartmut
N-(3-Chloro­phen­yl)maleamic acid
title N-(3-Chloro­phen­yl)maleamic acid
title_full N-(3-Chloro­phen­yl)maleamic acid
title_fullStr N-(3-Chloro­phen­yl)maleamic acid
title_full_unstemmed N-(3-Chloro­phen­yl)maleamic acid
title_short N-(3-Chloro­phen­yl)maleamic acid
title_sort n-(3-chloro­phen­yl)maleamic acid
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006958/
https://www.ncbi.nlm.nih.gov/pubmed/21587872
http://dx.doi.org/10.1107/S1600536810021446
work_keys_str_mv AT gowdabthimme n3chlorophenylmaleamicacid
AT tokarcikmiroslav n3chlorophenylmaleamicacid
AT shakuntalak n3chlorophenylmaleamicacid
AT kozisekjozef n3chlorophenylmaleamicacid
AT fuesshartmut n3chlorophenylmaleamicacid

Ejemplares similares