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Bis(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)bis(nitrato-κ(2) O,O′)lead(II)
In the title complex, [Pb(NO(3))(2)(C(14)H(12)N(2))(2)], the lead ion is chelated by two 2,9-dimethyl-1,10-phenanthroline (dmphen) ligands and two nitrate anions in a slightly distorted square-antiprismatic geometry. Intra- and intermolecular π–π stacking is present in the crystal structure, and t...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006962/ https://www.ncbi.nlm.nih.gov/pubmed/21587725 http://dx.doi.org/10.1107/S1600536810022312 |
| _version_ | 1782194264632983552 |
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| author | Shen, Fwu Ming Lush, Shie Fu |
| author_facet | Shen, Fwu Ming Lush, Shie Fu |
| author_sort | Shen, Fwu Ming |
| collection | PubMed |
| description | In the title complex, [Pb(NO(3))(2)(C(14)H(12)N(2))(2)], the lead ion is chelated by two 2,9-dimethyl-1,10-phenanthroline (dmphen) ligands and two nitrate anions in a slightly distorted square-antiprismatic geometry. Intra- and intermolecular π–π stacking is present in the crystal structure, and the centroid–centroid distances between the benzene and pyridine rings of adjacent dmphen ligands are 3.492 (3) and 3.592 (3) Å, respectively. Intermolecular C—H⋯O hydrogen bonds and C—H⋯π interactions help to stabilize the crystal structure. |
| format | Text |
| id | pubmed-3006962 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30069622010-12-30 Bis(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)bis(nitrato-κ(2) O,O′)lead(II) Shen, Fwu Ming Lush, Shie Fu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Pb(NO(3))(2)(C(14)H(12)N(2))(2)], the lead ion is chelated by two 2,9-dimethyl-1,10-phenanthroline (dmphen) ligands and two nitrate anions in a slightly distorted square-antiprismatic geometry. Intra- and intermolecular π–π stacking is present in the crystal structure, and the centroid–centroid distances between the benzene and pyridine rings of adjacent dmphen ligands are 3.492 (3) and 3.592 (3) Å, respectively. Intermolecular C—H⋯O hydrogen bonds and C—H⋯π interactions help to stabilize the crystal structure. International Union of Crystallography 2010-06-16 /pmc/articles/PMC3006962/ /pubmed/21587725 http://dx.doi.org/10.1107/S1600536810022312 Text en © Shen and Lush 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Shen, Fwu Ming Lush, Shie Fu Bis(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)bis(nitrato-κ(2) O,O′)lead(II) |
| title | Bis(2,9-dimethyl-1,10-phenanthroline-κ(2)
N,N′)bis(nitrato-κ(2)
O,O′)lead(II) |
| title_full | Bis(2,9-dimethyl-1,10-phenanthroline-κ(2)
N,N′)bis(nitrato-κ(2)
O,O′)lead(II) |
| title_fullStr | Bis(2,9-dimethyl-1,10-phenanthroline-κ(2)
N,N′)bis(nitrato-κ(2)
O,O′)lead(II) |
| title_full_unstemmed | Bis(2,9-dimethyl-1,10-phenanthroline-κ(2)
N,N′)bis(nitrato-κ(2)
O,O′)lead(II) |
| title_short | Bis(2,9-dimethyl-1,10-phenanthroline-κ(2)
N,N′)bis(nitrato-κ(2)
O,O′)lead(II) |
| title_sort | bis(2,9-dimethyl-1,10-phenanthroline-κ(2)
n,n′)bis(nitrato-κ(2)
o,o′)lead(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006962/ https://www.ncbi.nlm.nih.gov/pubmed/21587725 http://dx.doi.org/10.1107/S1600536810022312 |
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