Methyl 2,6-bis­[(5-bromo-4,6-dimeth­oxy­pyrimidin-2-yl)­oxy]benzoate

In the title compound, C(20)H(18)Br(2)N(4)O(8), the inter­planar angle of the pyrimidine rings is 75.1 (2)°. The central benzene ring is inclined at inter­planar angles of 66.5 (2) and 71.9 (2)° with respect to the two pyrimidine rings. In the crystal structure, adjacent mol­ecules are connected int...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Goh, Jia Hao, Rai, Sankappa, Isloor, Arun M., Shetty, Prakash
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006963/
https://www.ncbi.nlm.nih.gov/pubmed/21588067
http://dx.doi.org/10.1107/S1600536810024724
Descripción
Sumario:In the title compound, C(20)H(18)Br(2)N(4)O(8), the inter­planar angle of the pyrimidine rings is 75.1 (2)°. The central benzene ring is inclined at inter­planar angles of 66.5 (2) and 71.9 (2)° with respect to the two pyrimidine rings. In the crystal structure, adjacent mol­ecules are connected into two-mol­ecule-thick arrays parallel to the bc plane via short Br⋯Br [3.5328 (12) Å] and Br⋯O [3.206 (3) and 3.301 (4) Å] inter­actions. A weak inter­molecular π–π aromatic stacking inter­action [centroid–centroid distance = 3.526 (3) Å] is also observed.

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