Methyl 2,6-bis­[(5-bromo-4,6-dimeth­oxy­pyrimidin-2-yl)­oxy]benzoate

In the title compound, C(20)H(18)Br(2)N(4)O(8), the inter­planar angle of the pyrimidine rings is 75.1 (2)°. The central benzene ring is inclined at inter­planar angles of 66.5 (2) and 71.9 (2)° with respect to the two pyrimidine rings. In the crystal structure, adjacent mol­ecules are connected int...

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Autores principales: Fun, Hoong-Kun, Goh, Jia Hao, Rai, Sankappa, Isloor, Arun M., Shetty, Prakash
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006963/
https://www.ncbi.nlm.nih.gov/pubmed/21588067
http://dx.doi.org/10.1107/S1600536810024724
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author Fun, Hoong-Kun
Goh, Jia Hao
Rai, Sankappa
Isloor, Arun M.
Shetty, Prakash
author_facet Fun, Hoong-Kun
Goh, Jia Hao
Rai, Sankappa
Isloor, Arun M.
Shetty, Prakash
author_sort Fun, Hoong-Kun
collection PubMed
description In the title compound, C(20)H(18)Br(2)N(4)O(8), the inter­planar angle of the pyrimidine rings is 75.1 (2)°. The central benzene ring is inclined at inter­planar angles of 66.5 (2) and 71.9 (2)° with respect to the two pyrimidine rings. In the crystal structure, adjacent mol­ecules are connected into two-mol­ecule-thick arrays parallel to the bc plane via short Br⋯Br [3.5328 (12) Å] and Br⋯O [3.206 (3) and 3.301 (4) Å] inter­actions. A weak inter­molecular π–π aromatic stacking inter­action [centroid–centroid distance = 3.526 (3) Å] is also observed.
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spelling pubmed-30069632010-12-30 Methyl 2,6-bis­[(5-bromo-4,6-dimeth­oxy­pyrimidin-2-yl)­oxy]benzoate Fun, Hoong-Kun Goh, Jia Hao Rai, Sankappa Isloor, Arun M. Shetty, Prakash Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(20)H(18)Br(2)N(4)O(8), the inter­planar angle of the pyrimidine rings is 75.1 (2)°. The central benzene ring is inclined at inter­planar angles of 66.5 (2) and 71.9 (2)° with respect to the two pyrimidine rings. In the crystal structure, adjacent mol­ecules are connected into two-mol­ecule-thick arrays parallel to the bc plane via short Br⋯Br [3.5328 (12) Å] and Br⋯O [3.206 (3) and 3.301 (4) Å] inter­actions. A weak inter­molecular π–π aromatic stacking inter­action [centroid–centroid distance = 3.526 (3) Å] is also observed. International Union of Crystallography 2010-06-30 /pmc/articles/PMC3006963/ /pubmed/21588067 http://dx.doi.org/10.1107/S1600536810024724 Text en © Fun et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Goh, Jia Hao
Rai, Sankappa
Isloor, Arun M.
Shetty, Prakash
Methyl 2,6-bis­[(5-bromo-4,6-dimeth­oxy­pyrimidin-2-yl)­oxy]benzoate
title Methyl 2,6-bis­[(5-bromo-4,6-dimeth­oxy­pyrimidin-2-yl)­oxy]benzoate
title_full Methyl 2,6-bis­[(5-bromo-4,6-dimeth­oxy­pyrimidin-2-yl)­oxy]benzoate
title_fullStr Methyl 2,6-bis­[(5-bromo-4,6-dimeth­oxy­pyrimidin-2-yl)­oxy]benzoate
title_full_unstemmed Methyl 2,6-bis­[(5-bromo-4,6-dimeth­oxy­pyrimidin-2-yl)­oxy]benzoate
title_short Methyl 2,6-bis­[(5-bromo-4,6-dimeth­oxy­pyrimidin-2-yl)­oxy]benzoate
title_sort methyl 2,6-bis­[(5-bromo-4,6-dimeth­oxy­pyrimidin-2-yl)­oxy]benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006963/
https://www.ncbi.nlm.nih.gov/pubmed/21588067
http://dx.doi.org/10.1107/S1600536810024724
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