Bis(N,N′-diphenyl­benzamidinium) fumarate

The crystal structure of the title compound, 2C(19)H(17)N(2) (+)·C(4)H(2)O(4) (2−), consists of centrosymmetric trimers built up of two crystallographically independent N,N′-diphenyl­benzamid­in­ium cations and one fumarate dianion, which is located on a centre of inversion. The components of the tr...

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Detalles Bibliográficos
Autores principales: Orola, Liana, Veidis, Mikelis V.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006964/
https://www.ncbi.nlm.nih.gov/pubmed/21587834
http://dx.doi.org/10.1107/S1600536810017708
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author Orola, Liana
Veidis, Mikelis V.
author_facet Orola, Liana
Veidis, Mikelis V.
author_sort Orola, Liana
collection PubMed
description The crystal structure of the title compound, 2C(19)H(17)N(2) (+)·C(4)H(2)O(4) (2−), consists of centrosymmetric trimers built up of two crystallographically independent N,N′-diphenyl­benzamid­in­ium cations and one fumarate dianion, which is located on a centre of inversion. The components of the trimers are linked by N—H⋯O hydrogen bonding. In the cation, the outer rings make dihedral angles of 53.66 (5) and 78.38 (5)° with the central ring. The two outer rings make a dihdral angle of 81.49 (5)°.
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spelling pubmed-30069642010-12-30 Bis(N,N′-diphenyl­benzamidinium) fumarate Orola, Liana Veidis, Mikelis V. Acta Crystallogr Sect E Struct Rep Online Organic Papers The crystal structure of the title compound, 2C(19)H(17)N(2) (+)·C(4)H(2)O(4) (2−), consists of centrosymmetric trimers built up of two crystallographically independent N,N′-diphenyl­benzamid­in­ium cations and one fumarate dianion, which is located on a centre of inversion. The components of the trimers are linked by N—H⋯O hydrogen bonding. In the cation, the outer rings make dihedral angles of 53.66 (5) and 78.38 (5)° with the central ring. The two outer rings make a dihdral angle of 81.49 (5)°. International Union of Crystallography 2010-06-09 /pmc/articles/PMC3006964/ /pubmed/21587834 http://dx.doi.org/10.1107/S1600536810017708 Text en © Orola and Veidis 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Orola, Liana
Veidis, Mikelis V.
Bis(N,N′-diphenyl­benzamidinium) fumarate
title Bis(N,N′-diphenyl­benzamidinium) fumarate
title_full Bis(N,N′-diphenyl­benzamidinium) fumarate
title_fullStr Bis(N,N′-diphenyl­benzamidinium) fumarate
title_full_unstemmed Bis(N,N′-diphenyl­benzamidinium) fumarate
title_short Bis(N,N′-diphenyl­benzamidinium) fumarate
title_sort bis(n,n′-diphenyl­benzamidinium) fumarate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006964/
https://www.ncbi.nlm.nih.gov/pubmed/21587834
http://dx.doi.org/10.1107/S1600536810017708
work_keys_str_mv AT orolaliana bisnndiphenylbenzamidiniumfumarate
AT veidismikelisv bisnndiphenylbenzamidiniumfumarate

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