4-Fluoro­anilinium tetra­chloridoferrate(III) 18-crown-6 clathrate

The reaction of 4-fluoro­aniline hydro­chloride, 18-crown-6 and ferric chloride in methano­lic solution yields the title compound, (C(6)H(7)FN)[FeCl(4)]·C(12)H(24)O(6), which has an unusual supramolecular structure. N—H⋯O hydrogen-bonding inter­actions between the NH(3) (+) substituents of the 4-flu...

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Detalles Bibliográficos
Autores principales: Ge, Jia-Zhen, Zhao, Min-Min
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006967/
https://www.ncbi.nlm.nih.gov/pubmed/21587679
http://dx.doi.org/10.1107/S160053681002009X
Descripción
Sumario:The reaction of 4-fluoro­aniline hydro­chloride, 18-crown-6 and ferric chloride in methano­lic solution yields the title compound, (C(6)H(7)FN)[FeCl(4)]·C(12)H(24)O(6), which has an unusual supramolecular structure. N—H⋯O hydrogen-bonding inter­actions between the NH(3) (+) substituents of the 4-fluoro­anilinium cations and the O atoms of the crown ether mol­ecules result in a rotator–stator-like structure.

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