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4-Fluoroanilinium tetrachloridoferrate(III) 18-crown-6 clathrate
The reaction of 4-fluoroaniline hydrochloride, 18-crown-6 and ferric chloride in methanolic solution yields the title compound, (C(6)H(7)FN)[FeCl(4)]·C(12)H(24)O(6), which has an unusual supramolecular structure. N—H⋯O hydrogen-bonding interactions between the NH(3) (+) substituents of the 4-flu...
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006967/ https://www.ncbi.nlm.nih.gov/pubmed/21587679 http://dx.doi.org/10.1107/S160053681002009X |
| _version_ | 1782194265809485824 |
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| author | Ge, Jia-Zhen Zhao, Min-Min |
| author_facet | Ge, Jia-Zhen Zhao, Min-Min |
| author_sort | Ge, Jia-Zhen |
| collection | PubMed |
| description | The reaction of 4-fluoroaniline hydrochloride, 18-crown-6 and ferric chloride in methanolic solution yields the title compound, (C(6)H(7)FN)[FeCl(4)]·C(12)H(24)O(6), which has an unusual supramolecular structure. N—H⋯O hydrogen-bonding interactions between the NH(3) (+) substituents of the 4-fluoroanilinium cations and the O atoms of the crown ether molecules result in a rotator–stator-like structure. |
| format | Text |
| id | pubmed-3006967 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30069672010-12-30 4-Fluoroanilinium tetrachloridoferrate(III) 18-crown-6 clathrate Ge, Jia-Zhen Zhao, Min-Min Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The reaction of 4-fluoroaniline hydrochloride, 18-crown-6 and ferric chloride in methanolic solution yields the title compound, (C(6)H(7)FN)[FeCl(4)]·C(12)H(24)O(6), which has an unusual supramolecular structure. N—H⋯O hydrogen-bonding interactions between the NH(3) (+) substituents of the 4-fluoroanilinium cations and the O atoms of the crown ether molecules result in a rotator–stator-like structure. International Union of Crystallography 2010-06-05 /pmc/articles/PMC3006967/ /pubmed/21587679 http://dx.doi.org/10.1107/S160053681002009X Text en © Ge and Zhao 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Ge, Jia-Zhen Zhao, Min-Min 4-Fluoroanilinium tetrachloridoferrate(III) 18-crown-6 clathrate |
| title | 4-Fluoroanilinium tetrachloridoferrate(III) 18-crown-6 clathrate |
| title_full | 4-Fluoroanilinium tetrachloridoferrate(III) 18-crown-6 clathrate |
| title_fullStr | 4-Fluoroanilinium tetrachloridoferrate(III) 18-crown-6 clathrate |
| title_full_unstemmed | 4-Fluoroanilinium tetrachloridoferrate(III) 18-crown-6 clathrate |
| title_short | 4-Fluoroanilinium tetrachloridoferrate(III) 18-crown-6 clathrate |
| title_sort | 4-fluoroanilinium tetrachloridoferrate(iii) 18-crown-6 clathrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006967/ https://www.ncbi.nlm.nih.gov/pubmed/21587679 http://dx.doi.org/10.1107/S160053681002009X |
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