1,5-Dimethyl-3-propargyl-1H-1,5-benzodiazepine-2,4(3H,5H)-dione

The asymmetric unit of the title compound, C(14)H(14)N(2)O(2), comprises two independent mol­ecules, which slightly differ in the orientation of the propargyl chain. In both molecules, the diazepine ring adopts a boat conformation with the propargyl-bearing C atom as the prow and the C atoms at the...

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Autores principales: Dardouri, Rachid, Ouazzani Chahdi, F., Saffon, Natalie, Essassi, El Mokhtar, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006968/
https://www.ncbi.nlm.nih.gov/pubmed/21588007
http://dx.doi.org/10.1107/S1600536810024219
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author Dardouri, Rachid
Ouazzani Chahdi, F.
Saffon, Natalie
Essassi, El Mokhtar
Ng, Seik Weng
author_facet Dardouri, Rachid
Ouazzani Chahdi, F.
Saffon, Natalie
Essassi, El Mokhtar
Ng, Seik Weng
author_sort Dardouri, Rachid
collection PubMed
description The asymmetric unit of the title compound, C(14)H(14)N(2)O(2), comprises two independent mol­ecules, which slightly differ in the orientation of the propargyl chain. In both molecules, the diazepine ring adopts a boat conformation with the propargyl-bearing C atom as the prow and the C atoms at the ring junction as the stern. The carbonyl O atom of one independent mol­ecule is hydrogen bonded to the acetyl­enic H atom of the other independent mol­ecule. In the crystal, symmetry-related mol­ecules are linked together by C—H⋯O hydrogen bonds, forming a ribbon-like structure along the c axis.
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spelling pubmed-30069682010-12-30 1,5-Dimethyl-3-propargyl-1H-1,5-benzodiazepine-2,4(3H,5H)-dione Dardouri, Rachid Ouazzani Chahdi, F. Saffon, Natalie Essassi, El Mokhtar Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(14)H(14)N(2)O(2), comprises two independent mol­ecules, which slightly differ in the orientation of the propargyl chain. In both molecules, the diazepine ring adopts a boat conformation with the propargyl-bearing C atom as the prow and the C atoms at the ring junction as the stern. The carbonyl O atom of one independent mol­ecule is hydrogen bonded to the acetyl­enic H atom of the other independent mol­ecule. In the crystal, symmetry-related mol­ecules are linked together by C—H⋯O hydrogen bonds, forming a ribbon-like structure along the c axis. International Union of Crystallography 2010-06-26 /pmc/articles/PMC3006968/ /pubmed/21588007 http://dx.doi.org/10.1107/S1600536810024219 Text en © Dardouri et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Dardouri, Rachid
Ouazzani Chahdi, F.
Saffon, Natalie
Essassi, El Mokhtar
Ng, Seik Weng
1,5-Dimethyl-3-propargyl-1H-1,5-benzodiazepine-2,4(3H,5H)-dione
title 1,5-Dimethyl-3-propargyl-1H-1,5-benzodiazepine-2,4(3H,5H)-dione
title_full 1,5-Dimethyl-3-propargyl-1H-1,5-benzodiazepine-2,4(3H,5H)-dione
title_fullStr 1,5-Dimethyl-3-propargyl-1H-1,5-benzodiazepine-2,4(3H,5H)-dione
title_full_unstemmed 1,5-Dimethyl-3-propargyl-1H-1,5-benzodiazepine-2,4(3H,5H)-dione
title_short 1,5-Dimethyl-3-propargyl-1H-1,5-benzodiazepine-2,4(3H,5H)-dione
title_sort 1,5-dimethyl-3-propargyl-1h-1,5-benzodiazepine-2,4(3h,5h)-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006968/
https://www.ncbi.nlm.nih.gov/pubmed/21588007
http://dx.doi.org/10.1107/S1600536810024219
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