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A monoclinic modification of 2-[(1,3-benzothiazol-2-yl)iminomethyl]phenol
In the title Schiff base, C(14)H(10)N(2)OS, the azomethine double bond is in an E configuration; the benzothiazolyl ring (r.m.s. deviation = 0.007 Å) is coplanar with the phenylene ring (r.m.s. deviation = 0.007 Å), the two rings being slightly bent at 2.6 (1)°. The hydroxy H atom forms an intram...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006974/ https://www.ncbi.nlm.nih.gov/pubmed/21588032 http://dx.doi.org/10.1107/S1600536810023755 |
Sumario: | In the title Schiff base, C(14)H(10)N(2)OS, the azomethine double bond is in an E configuration; the benzothiazolyl ring (r.m.s. deviation = 0.007 Å) is coplanar with the phenylene ring (r.m.s. deviation = 0.007 Å), the two rings being slightly bent at 2.6 (1)°. The hydroxy H atom forms an intramolecular hydrogen bond to the imino group. The bond dimensions of the monoclinic modification are similar to those of the orthorhombic modification [Liu et al. (2009 ▶). Acta Cryst. E65, o738]. |
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