A monoclinic modification of 2-[(1,3-benzothia­zol-2-yl)imino­meth­yl]phenol

In the title Schiff base, C(14)H(10)N(2)OS, the azomethine double bond is in an E configuration; the benzothiazolyl ring (r.m.s. deviation = 0.007 Å) is coplanar with the phenyl­ene ring (r.m.s. deviation = 0.007 Å), the two rings being slightly bent at 2.6 (1)°. The hy­droxy H atom forms an intra­m...

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Detalles Bibliográficos
Autores principales: Asiri, Abdullah M., Khan, Salman A., Tan, Kong Wai, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006974/
https://www.ncbi.nlm.nih.gov/pubmed/21588032
http://dx.doi.org/10.1107/S1600536810023755
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author Asiri, Abdullah M.
Khan, Salman A.
Tan, Kong Wai
Ng, Seik Weng
author_facet Asiri, Abdullah M.
Khan, Salman A.
Tan, Kong Wai
Ng, Seik Weng
author_sort Asiri, Abdullah M.
collection PubMed
description In the title Schiff base, C(14)H(10)N(2)OS, the azomethine double bond is in an E configuration; the benzothiazolyl ring (r.m.s. deviation = 0.007 Å) is coplanar with the phenyl­ene ring (r.m.s. deviation = 0.007 Å), the two rings being slightly bent at 2.6 (1)°. The hy­droxy H atom forms an intra­molecular hydrogen bond to the imino group. The bond dimensions of the monoclinic modification are similar to those of the ortho­rhom­bic modification [Liu et al. (2009 ▶). Acta Cryst. E65, o738].
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spelling pubmed-30069742010-12-30 A monoclinic modification of 2-[(1,3-benzothia­zol-2-yl)imino­meth­yl]phenol Asiri, Abdullah M. Khan, Salman A. Tan, Kong Wai Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title Schiff base, C(14)H(10)N(2)OS, the azomethine double bond is in an E configuration; the benzothiazolyl ring (r.m.s. deviation = 0.007 Å) is coplanar with the phenyl­ene ring (r.m.s. deviation = 0.007 Å), the two rings being slightly bent at 2.6 (1)°. The hy­droxy H atom forms an intra­molecular hydrogen bond to the imino group. The bond dimensions of the monoclinic modification are similar to those of the ortho­rhom­bic modification [Liu et al. (2009 ▶). Acta Cryst. E65, o738]. International Union of Crystallography 2010-06-26 /pmc/articles/PMC3006974/ /pubmed/21588032 http://dx.doi.org/10.1107/S1600536810023755 Text en © Asiri et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Asiri, Abdullah M.
Khan, Salman A.
Tan, Kong Wai
Ng, Seik Weng
A monoclinic modification of 2-[(1,3-benzothia­zol-2-yl)imino­meth­yl]phenol
title A monoclinic modification of 2-[(1,3-benzothia­zol-2-yl)imino­meth­yl]phenol
title_full A monoclinic modification of 2-[(1,3-benzothia­zol-2-yl)imino­meth­yl]phenol
title_fullStr A monoclinic modification of 2-[(1,3-benzothia­zol-2-yl)imino­meth­yl]phenol
title_full_unstemmed A monoclinic modification of 2-[(1,3-benzothia­zol-2-yl)imino­meth­yl]phenol
title_short A monoclinic modification of 2-[(1,3-benzothia­zol-2-yl)imino­meth­yl]phenol
title_sort monoclinic modification of 2-[(1,3-benzothia­zol-2-yl)imino­meth­yl]phenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006974/
https://www.ncbi.nlm.nih.gov/pubmed/21588032
http://dx.doi.org/10.1107/S1600536810023755
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