Tetra­ethyl­ammonium bromidotricarbon­yl(tropolonato)rhenate(I)

In the title salt, (C(8)H(20)N)[ReBr(C(7)H(5)O(2))(CO)(3)], the Re(I) atom is octa­hedrally surrounded by three facially orientated carbonyl ligands, one bidendate tropolonate ligand and a bromide ligand. The small O—Re—O bite angle of 74.88 (12)° leads to a distortion of the octa­hedral coordinatio...

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Detalles Bibliográficos
Autores principales: Schutte, Marietjie, Visser, Hendrik G, Roodt, Andreas
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006975/
https://www.ncbi.nlm.nih.gov/pubmed/21587765
http://dx.doi.org/10.1107/S1600536810024505
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author Schutte, Marietjie
Visser, Hendrik G
Roodt, Andreas
author_facet Schutte, Marietjie
Visser, Hendrik G
Roodt, Andreas
author_sort Schutte, Marietjie
collection PubMed
description In the title salt, (C(8)H(20)N)[ReBr(C(7)H(5)O(2))(CO)(3)], the Re(I) atom is octa­hedrally surrounded by three facially orientated carbonyl ligands, one bidendate tropolonate ligand and a bromide ligand. The small O—Re—O bite angle of 74.88 (12)° leads to a distortion of the octa­hedral coordination sphere. The bromide ligand and the axial carbonyl ligand are substitutionally disordered over two positions in a 0.922 (3):0.078 (3) ratio. An array of C—H⋯O and C—H⋯Br hydrogen-bonding inter­actions between the cations and neighbouring rhenate anions stabilizes the crystal packing.
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spelling pubmed-30069752010-12-30 Tetra­ethyl­ammonium bromidotricarbon­yl(tropolonato)rhenate(I) Schutte, Marietjie Visser, Hendrik G Roodt, Andreas Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title salt, (C(8)H(20)N)[ReBr(C(7)H(5)O(2))(CO)(3)], the Re(I) atom is octa­hedrally surrounded by three facially orientated carbonyl ligands, one bidendate tropolonate ligand and a bromide ligand. The small O—Re—O bite angle of 74.88 (12)° leads to a distortion of the octa­hedral coordination sphere. The bromide ligand and the axial carbonyl ligand are substitutionally disordered over two positions in a 0.922 (3):0.078 (3) ratio. An array of C—H⋯O and C—H⋯Br hydrogen-bonding inter­actions between the cations and neighbouring rhenate anions stabilizes the crystal packing. International Union of Crystallography 2010-06-26 /pmc/articles/PMC3006975/ /pubmed/21587765 http://dx.doi.org/10.1107/S1600536810024505 Text en © Schutte et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Schutte, Marietjie
Visser, Hendrik G
Roodt, Andreas
Tetra­ethyl­ammonium bromidotricarbon­yl(tropolonato)rhenate(I)
title Tetra­ethyl­ammonium bromidotricarbon­yl(tropolonato)rhenate(I)
title_full Tetra­ethyl­ammonium bromidotricarbon­yl(tropolonato)rhenate(I)
title_fullStr Tetra­ethyl­ammonium bromidotricarbon­yl(tropolonato)rhenate(I)
title_full_unstemmed Tetra­ethyl­ammonium bromidotricarbon­yl(tropolonato)rhenate(I)
title_short Tetra­ethyl­ammonium bromidotricarbon­yl(tropolonato)rhenate(I)
title_sort tetra­ethyl­ammonium bromidotricarbon­yl(tropolonato)rhenate(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006975/
https://www.ncbi.nlm.nih.gov/pubmed/21587765
http://dx.doi.org/10.1107/S1600536810024505
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AT visserhendrikg tetraethylammoniumbromidotricarbonyltropolonatorhenatei
AT roodtandreas tetraethylammoniumbromidotricarbonyltropolonatorhenatei

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