Bis(μ-4-phenyl­pyridine N-oxide-κ(2) O:O)bis­[bis­(1,1,1,5,5,5-hexa­fluoro­pentane-2,4-dionato)copper(II)]

The asymmetric unit of the title compound, [Cu(2)(C(5)HF(6)O(2))(4)(C(11)H(9)NO)(2)], contains one half of the centrosymmetric dinuclear complex. The coordination geometry of the Cu(II) atom is octa­hedral, exhibiting a typical Jahn–Teller distortion. One trifluoro­methyl group is rotationally disor...

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Detalles Bibliográficos
Autores principales: Ramos, Ana I., Fernandes, José A., Silva, Patrícia, Ribeiro-Claro, Paulo J. A., Braga, Susana S., Almeida Paz, Filipe A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006976/
https://www.ncbi.nlm.nih.gov/pubmed/21587739
http://dx.doi.org/10.1107/S1600536810022567
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author Ramos, Ana I.
Fernandes, José A.
Silva, Patrícia
Ribeiro-Claro, Paulo J. A.
Braga, Susana S.
Almeida Paz, Filipe A.
author_facet Ramos, Ana I.
Fernandes, José A.
Silva, Patrícia
Ribeiro-Claro, Paulo J. A.
Braga, Susana S.
Almeida Paz, Filipe A.
author_sort Ramos, Ana I.
collection PubMed
description The asymmetric unit of the title compound, [Cu(2)(C(5)HF(6)O(2))(4)(C(11)H(9)NO)(2)], contains one half of the centrosymmetric dinuclear complex. The coordination geometry of the Cu(II) atom is octa­hedral, exhibiting a typical Jahn–Teller distortion. One trifluoro­methyl group is rotationally disordered between two orientations in a 1:1 ratio.
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spelling pubmed-30069762010-12-30 Bis(μ-4-phenyl­pyridine N-oxide-κ(2) O:O)bis­[bis­(1,1,1,5,5,5-hexa­fluoro­pentane-2,4-dionato)copper(II)] Ramos, Ana I. Fernandes, José A. Silva, Patrícia Ribeiro-Claro, Paulo J. A. Braga, Susana S. Almeida Paz, Filipe A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Cu(2)(C(5)HF(6)O(2))(4)(C(11)H(9)NO)(2)], contains one half of the centrosymmetric dinuclear complex. The coordination geometry of the Cu(II) atom is octa­hedral, exhibiting a typical Jahn–Teller distortion. One trifluoro­methyl group is rotationally disordered between two orientations in a 1:1 ratio. International Union of Crystallography 2010-06-23 /pmc/articles/PMC3006976/ /pubmed/21587739 http://dx.doi.org/10.1107/S1600536810022567 Text en © Ramos et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ramos, Ana I.
Fernandes, José A.
Silva, Patrícia
Ribeiro-Claro, Paulo J. A.
Braga, Susana S.
Almeida Paz, Filipe A.
Bis(μ-4-phenyl­pyridine N-oxide-κ(2) O:O)bis­[bis­(1,1,1,5,5,5-hexa­fluoro­pentane-2,4-dionato)copper(II)]
title Bis(μ-4-phenyl­pyridine N-oxide-κ(2) O:O)bis­[bis­(1,1,1,5,5,5-hexa­fluoro­pentane-2,4-dionato)copper(II)]
title_full Bis(μ-4-phenyl­pyridine N-oxide-κ(2) O:O)bis­[bis­(1,1,1,5,5,5-hexa­fluoro­pentane-2,4-dionato)copper(II)]
title_fullStr Bis(μ-4-phenyl­pyridine N-oxide-κ(2) O:O)bis­[bis­(1,1,1,5,5,5-hexa­fluoro­pentane-2,4-dionato)copper(II)]
title_full_unstemmed Bis(μ-4-phenyl­pyridine N-oxide-κ(2) O:O)bis­[bis­(1,1,1,5,5,5-hexa­fluoro­pentane-2,4-dionato)copper(II)]
title_short Bis(μ-4-phenyl­pyridine N-oxide-κ(2) O:O)bis­[bis­(1,1,1,5,5,5-hexa­fluoro­pentane-2,4-dionato)copper(II)]
title_sort bis(μ-4-phenyl­pyridine n-oxide-κ(2) o:o)bis­[bis­(1,1,1,5,5,5-hexa­fluoro­pentane-2,4-dionato)copper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006976/
https://www.ncbi.nlm.nih.gov/pubmed/21587739
http://dx.doi.org/10.1107/S1600536810022567
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