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Acetatoaqua{4,4′,6,6′-tetra-tert-butyl-2,2′-[(2-pyridylmethyl)iminodimethylene]diphenolato}manganese(III) ethanol solvate
In the title complex, [Mn(C(36)H(50)N(2)O(2))(CH(3)COO)(H(2)O)]·CH(3)CH(2)OH, the Mn(III) atom is in an octahedral environment and is coordinated by the tetradentate amine–bis(phenolate) ligand, a monodentate acetate anion and a water molecule. An ethanol solvent molecule is also found in the a...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006980/ https://www.ncbi.nlm.nih.gov/pubmed/21587701 http://dx.doi.org/10.1107/S1600536810021288 |
| _version_ | 1782194268940533760 |
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| author | Chard, Elliott Dawe, Louise N. Kozak, Christopher M. |
| author_facet | Chard, Elliott Dawe, Louise N. Kozak, Christopher M. |
| author_sort | Chard, Elliott |
| collection | PubMed |
| description | In the title complex, [Mn(C(36)H(50)N(2)O(2))(CH(3)COO)(H(2)O)]·CH(3)CH(2)OH, the Mn(III) atom is in an octahedral environment and is coordinated by the tetradentate amine–bis(phenolate) ligand, a monodentate acetate anion and a water molecule. An ethanol solvent molecule is also found in the asymmetric unit. The structure displays O—H⋯O and C—H⋯O hydrogen bonding. |
| format | Text |
| id | pubmed-3006980 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30069802010-12-30 Acetatoaqua{4,4′,6,6′-tetra-tert-butyl-2,2′-[(2-pyridylmethyl)iminodimethylene]diphenolato}manganese(III) ethanol solvate Chard, Elliott Dawe, Louise N. Kozak, Christopher M. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Mn(C(36)H(50)N(2)O(2))(CH(3)COO)(H(2)O)]·CH(3)CH(2)OH, the Mn(III) atom is in an octahedral environment and is coordinated by the tetradentate amine–bis(phenolate) ligand, a monodentate acetate anion and a water molecule. An ethanol solvent molecule is also found in the asymmetric unit. The structure displays O—H⋯O and C—H⋯O hydrogen bonding. International Union of Crystallography 2010-06-16 /pmc/articles/PMC3006980/ /pubmed/21587701 http://dx.doi.org/10.1107/S1600536810021288 Text en © Chard et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Chard, Elliott Dawe, Louise N. Kozak, Christopher M. Acetatoaqua{4,4′,6,6′-tetra-tert-butyl-2,2′-[(2-pyridylmethyl)iminodimethylene]diphenolato}manganese(III) ethanol solvate |
| title | Acetatoaqua{4,4′,6,6′-tetra-tert-butyl-2,2′-[(2-pyridylmethyl)iminodimethylene]diphenolato}manganese(III) ethanol solvate |
| title_full | Acetatoaqua{4,4′,6,6′-tetra-tert-butyl-2,2′-[(2-pyridylmethyl)iminodimethylene]diphenolato}manganese(III) ethanol solvate |
| title_fullStr | Acetatoaqua{4,4′,6,6′-tetra-tert-butyl-2,2′-[(2-pyridylmethyl)iminodimethylene]diphenolato}manganese(III) ethanol solvate |
| title_full_unstemmed | Acetatoaqua{4,4′,6,6′-tetra-tert-butyl-2,2′-[(2-pyridylmethyl)iminodimethylene]diphenolato}manganese(III) ethanol solvate |
| title_short | Acetatoaqua{4,4′,6,6′-tetra-tert-butyl-2,2′-[(2-pyridylmethyl)iminodimethylene]diphenolato}manganese(III) ethanol solvate |
| title_sort | acetatoaqua{4,4′,6,6′-tetra-tert-butyl-2,2′-[(2-pyridylmethyl)iminodimethylene]diphenolato}manganese(iii) ethanol solvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006980/ https://www.ncbi.nlm.nih.gov/pubmed/21587701 http://dx.doi.org/10.1107/S1600536810021288 |
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