Cargando…

catena-Poly[[diaqua­bis­(isoquinoline-κN)cobalt(II)]-μ-succinato-κ(2) O (1):O (4)]

In the title compound, [Co(C(4)H(4)O(4))(C(9)H(7)N)(2)(H(2)O)(2)](n), the Co(II) cation, located on an inversion center, is coordinated by two succinate anions, two isoquinoline ligands and two water mol­ecules in a distorted octa­hedral geometry. The succinate anion, located across another inversio...

Descripción completa

Detalles Bibliográficos
Autores principales: Li, Meng-Jiao, Nie, Jing-Jing, Xu, Duan-Jun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006983/
https://www.ncbi.nlm.nih.gov/pubmed/21587752
http://dx.doi.org/10.1107/S1600536810023895
Descripción
Sumario:In the title compound, [Co(C(4)H(4)O(4))(C(9)H(7)N)(2)(H(2)O)(2)](n), the Co(II) cation, located on an inversion center, is coordinated by two succinate anions, two isoquinoline ligands and two water mol­ecules in a distorted octa­hedral geometry. The succinate anion, located across another inversion center, bridges the Co cations, forming polymeric chains running along the b axis. The partially overlapped arrangement of parallel isoquinoline ring systems of adjacent polymeric chains and the shorter face-to-face distance of 3.402 (6) Å indicates the existence of weak π–π stacking in the crystal structure. Classical intra- and inter­molecular O—H⋯O hydrogen bonding and weak non-classical inter­molecular C—H⋯O hydrogen bonding help to stabilize the crystal structure.