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catena-Poly[[diaquabis(isoquinoline-κN)cobalt(II)]-μ-succinato-κ(2) O (1):O (4)]
In the title compound, [Co(C(4)H(4)O(4))(C(9)H(7)N)(2)(H(2)O)(2)](n), the Co(II) cation, located on an inversion center, is coordinated by two succinate anions, two isoquinoline ligands and two water molecules in a distorted octahedral geometry. The succinate anion, located across another inversio...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006983/ https://www.ncbi.nlm.nih.gov/pubmed/21587752 http://dx.doi.org/10.1107/S1600536810023895 |
Sumario: | In the title compound, [Co(C(4)H(4)O(4))(C(9)H(7)N)(2)(H(2)O)(2)](n), the Co(II) cation, located on an inversion center, is coordinated by two succinate anions, two isoquinoline ligands and two water molecules in a distorted octahedral geometry. The succinate anion, located across another inversion center, bridges the Co cations, forming polymeric chains running along the b axis. The partially overlapped arrangement of parallel isoquinoline ring systems of adjacent polymeric chains and the shorter face-to-face distance of 3.402 (6) Å indicates the existence of weak π–π stacking in the crystal structure. Classical intra- and intermolecular O—H⋯O hydrogen bonding and weak non-classical intermolecular C—H⋯O hydrogen bonding help to stabilize the crystal structure. |
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