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catena-Poly[[diaquabis(isoquinoline-κN)cobalt(II)]-μ-succinato-κ(2) O (1):O (4)]
In the title compound, [Co(C(4)H(4)O(4))(C(9)H(7)N)(2)(H(2)O)(2)](n), the Co(II) cation, located on an inversion center, is coordinated by two succinate anions, two isoquinoline ligands and two water molecules in a distorted octahedral geometry. The succinate anion, located across another inversio...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006983/ https://www.ncbi.nlm.nih.gov/pubmed/21587752 http://dx.doi.org/10.1107/S1600536810023895 |
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author | Li, Meng-Jiao Nie, Jing-Jing Xu, Duan-Jun |
author_facet | Li, Meng-Jiao Nie, Jing-Jing Xu, Duan-Jun |
author_sort | Li, Meng-Jiao |
collection | PubMed |
description | In the title compound, [Co(C(4)H(4)O(4))(C(9)H(7)N)(2)(H(2)O)(2)](n), the Co(II) cation, located on an inversion center, is coordinated by two succinate anions, two isoquinoline ligands and two water molecules in a distorted octahedral geometry. The succinate anion, located across another inversion center, bridges the Co cations, forming polymeric chains running along the b axis. The partially overlapped arrangement of parallel isoquinoline ring systems of adjacent polymeric chains and the shorter face-to-face distance of 3.402 (6) Å indicates the existence of weak π–π stacking in the crystal structure. Classical intra- and intermolecular O—H⋯O hydrogen bonding and weak non-classical intermolecular C—H⋯O hydrogen bonding help to stabilize the crystal structure. |
format | Text |
id | pubmed-3006983 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30069832010-12-30 catena-Poly[[diaquabis(isoquinoline-κN)cobalt(II)]-μ-succinato-κ(2) O (1):O (4)] Li, Meng-Jiao Nie, Jing-Jing Xu, Duan-Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(4)H(4)O(4))(C(9)H(7)N)(2)(H(2)O)(2)](n), the Co(II) cation, located on an inversion center, is coordinated by two succinate anions, two isoquinoline ligands and two water molecules in a distorted octahedral geometry. The succinate anion, located across another inversion center, bridges the Co cations, forming polymeric chains running along the b axis. The partially overlapped arrangement of parallel isoquinoline ring systems of adjacent polymeric chains and the shorter face-to-face distance of 3.402 (6) Å indicates the existence of weak π–π stacking in the crystal structure. Classical intra- and intermolecular O—H⋯O hydrogen bonding and weak non-classical intermolecular C—H⋯O hydrogen bonding help to stabilize the crystal structure. International Union of Crystallography 2010-06-26 /pmc/articles/PMC3006983/ /pubmed/21587752 http://dx.doi.org/10.1107/S1600536810023895 Text en © Li et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Li, Meng-Jiao Nie, Jing-Jing Xu, Duan-Jun catena-Poly[[diaquabis(isoquinoline-κN)cobalt(II)]-μ-succinato-κ(2) O (1):O (4)] |
title |
catena-Poly[[diaquabis(isoquinoline-κN)cobalt(II)]-μ-succinato-κ(2)
O
(1):O
(4)] |
title_full |
catena-Poly[[diaquabis(isoquinoline-κN)cobalt(II)]-μ-succinato-κ(2)
O
(1):O
(4)] |
title_fullStr |
catena-Poly[[diaquabis(isoquinoline-κN)cobalt(II)]-μ-succinato-κ(2)
O
(1):O
(4)] |
title_full_unstemmed |
catena-Poly[[diaquabis(isoquinoline-κN)cobalt(II)]-μ-succinato-κ(2)
O
(1):O
(4)] |
title_short |
catena-Poly[[diaquabis(isoquinoline-κN)cobalt(II)]-μ-succinato-κ(2)
O
(1):O
(4)] |
title_sort | catena-poly[[diaquabis(isoquinoline-κn)cobalt(ii)]-μ-succinato-κ(2)
o
(1):o
(4)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006983/ https://www.ncbi.nlm.nih.gov/pubmed/21587752 http://dx.doi.org/10.1107/S1600536810023895 |
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