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{N,N′-Bis[1-(2-pyridyl)ethylidene]propane-1,2-diamine-κ(4) N,N′,N′′,N′′′}bis(thiocyanato-κN)manganese(II)
In the title compound, [Mn(NCS)(2)(C(17)H(20)N(4))], the Mn(II) atom is six-coordinated by the N,N′,N′′,N′′′-tetradentate Schiff base ligand and by two trans-N atoms from two thiocyanate anions, forming a distorted octahedral geometry. The dihedral angle between the aromatic rings of the Schiff b...
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006985/ https://www.ncbi.nlm.nih.gov/pubmed/21587705 http://dx.doi.org/10.1107/S1600536810021549 |
| _version_ | 1782194270099210240 |
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| author | Wang, Fu-Ming |
| author_facet | Wang, Fu-Ming |
| author_sort | Wang, Fu-Ming |
| collection | PubMed |
| description | In the title compound, [Mn(NCS)(2)(C(17)H(20)N(4))], the Mn(II) atom is six-coordinated by the N,N′,N′′,N′′′-tetradentate Schiff base ligand and by two trans-N atoms from two thiocyanate anions, forming a distorted octahedral geometry. The dihedral angle between the aromatic rings of the Schiff base is 9.5 (3)°. |
| format | Text |
| id | pubmed-3006985 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30069852010-12-30 {N,N′-Bis[1-(2-pyridyl)ethylidene]propane-1,2-diamine-κ(4) N,N′,N′′,N′′′}bis(thiocyanato-κN)manganese(II) Wang, Fu-Ming Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(NCS)(2)(C(17)H(20)N(4))], the Mn(II) atom is six-coordinated by the N,N′,N′′,N′′′-tetradentate Schiff base ligand and by two trans-N atoms from two thiocyanate anions, forming a distorted octahedral geometry. The dihedral angle between the aromatic rings of the Schiff base is 9.5 (3)°. International Union of Crystallography 2010-06-16 /pmc/articles/PMC3006985/ /pubmed/21587705 http://dx.doi.org/10.1107/S1600536810021549 Text en © Fu-Ming Wang 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Wang, Fu-Ming {N,N′-Bis[1-(2-pyridyl)ethylidene]propane-1,2-diamine-κ(4) N,N′,N′′,N′′′}bis(thiocyanato-κN)manganese(II) |
| title | {N,N′-Bis[1-(2-pyridyl)ethylidene]propane-1,2-diamine-κ(4)
N,N′,N′′,N′′′}bis(thiocyanato-κN)manganese(II) |
| title_full | {N,N′-Bis[1-(2-pyridyl)ethylidene]propane-1,2-diamine-κ(4)
N,N′,N′′,N′′′}bis(thiocyanato-κN)manganese(II) |
| title_fullStr | {N,N′-Bis[1-(2-pyridyl)ethylidene]propane-1,2-diamine-κ(4)
N,N′,N′′,N′′′}bis(thiocyanato-κN)manganese(II) |
| title_full_unstemmed | {N,N′-Bis[1-(2-pyridyl)ethylidene]propane-1,2-diamine-κ(4)
N,N′,N′′,N′′′}bis(thiocyanato-κN)manganese(II) |
| title_short | {N,N′-Bis[1-(2-pyridyl)ethylidene]propane-1,2-diamine-κ(4)
N,N′,N′′,N′′′}bis(thiocyanato-κN)manganese(II) |
| title_sort | {n,n′-bis[1-(2-pyridyl)ethylidene]propane-1,2-diamine-κ(4)
n,n′,n′′,n′′′}bis(thiocyanato-κn)manganese(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006985/ https://www.ncbi.nlm.nih.gov/pubmed/21587705 http://dx.doi.org/10.1107/S1600536810021549 |
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