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N′-[(E)-1-(5-Chloro-2-hy­droxy­phen­yl)ethyl­idene]pyridine-3-carbohydrazide monohydrate

In the title compound, C(14)H(12)ClN(3)O(2)·H(2)O, the benzene ring and the pyridine rings are oriented at a dihedral angle of 57.73 (12)° and an intra­molecular O—H⋯N hydrogen bond generates an S(6) ring. In the crystal, the water mol­ecule forms O—H⋯O and O—H⋯N hydrogen bonds to the organic mol­ec...

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Detalles Bibliográficos
Autores principales: Hussain, Abid, Shafiq, Zahid, Tahir, M. Nawaz, Yaqub, Muhammad
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006986/
https://www.ncbi.nlm.nih.gov/pubmed/21588074
http://dx.doi.org/10.1107/S1600536810025213
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author Hussain, Abid
Shafiq, Zahid
Tahir, M. Nawaz
Yaqub, Muhammad
author_facet Hussain, Abid
Shafiq, Zahid
Tahir, M. Nawaz
Yaqub, Muhammad
author_sort Hussain, Abid
collection PubMed
description In the title compound, C(14)H(12)ClN(3)O(2)·H(2)O, the benzene ring and the pyridine rings are oriented at a dihedral angle of 57.73 (12)° and an intra­molecular O—H⋯N hydrogen bond generates an S(6) ring. In the crystal, the water mol­ecule forms O—H⋯O and O—H⋯N hydrogen bonds to the organic mol­ecule, leading to chains containing R (4) (4)(16) loops. In addition, weak aromatic π–π stacking inter­actions between the centroids of pyridine rings [at distance of 3.864 (2) and 4.013 (2) Å] and C—H⋯π inter­actions occur.
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spelling pubmed-30069862010-12-30 N′-[(E)-1-(5-Chloro-2-hy­droxy­phen­yl)ethyl­idene]pyridine-3-carbohydrazide monohydrate Hussain, Abid Shafiq, Zahid Tahir, M. Nawaz Yaqub, Muhammad Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(12)ClN(3)O(2)·H(2)O, the benzene ring and the pyridine rings are oriented at a dihedral angle of 57.73 (12)° and an intra­molecular O—H⋯N hydrogen bond generates an S(6) ring. In the crystal, the water mol­ecule forms O—H⋯O and O—H⋯N hydrogen bonds to the organic mol­ecule, leading to chains containing R (4) (4)(16) loops. In addition, weak aromatic π–π stacking inter­actions between the centroids of pyridine rings [at distance of 3.864 (2) and 4.013 (2) Å] and C—H⋯π inter­actions occur. International Union of Crystallography 2010-06-30 /pmc/articles/PMC3006986/ /pubmed/21588074 http://dx.doi.org/10.1107/S1600536810025213 Text en © Hussain et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hussain, Abid
Shafiq, Zahid
Tahir, M. Nawaz
Yaqub, Muhammad
N′-[(E)-1-(5-Chloro-2-hy­droxy­phen­yl)ethyl­idene]pyridine-3-carbohydrazide monohydrate
title N′-[(E)-1-(5-Chloro-2-hy­droxy­phen­yl)ethyl­idene]pyridine-3-carbohydrazide monohydrate
title_full N′-[(E)-1-(5-Chloro-2-hy­droxy­phen­yl)ethyl­idene]pyridine-3-carbohydrazide monohydrate
title_fullStr N′-[(E)-1-(5-Chloro-2-hy­droxy­phen­yl)ethyl­idene]pyridine-3-carbohydrazide monohydrate
title_full_unstemmed N′-[(E)-1-(5-Chloro-2-hy­droxy­phen­yl)ethyl­idene]pyridine-3-carbohydrazide monohydrate
title_short N′-[(E)-1-(5-Chloro-2-hy­droxy­phen­yl)ethyl­idene]pyridine-3-carbohydrazide monohydrate
title_sort n′-[(e)-1-(5-chloro-2-hy­droxy­phen­yl)ethyl­idene]pyridine-3-carbohydrazide monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006986/
https://www.ncbi.nlm.nih.gov/pubmed/21588074
http://dx.doi.org/10.1107/S1600536810025213
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