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N′-[(E)-1-(5-Chloro-2-hydroxyphenyl)ethylidene]pyridine-3-carbohydrazide monohydrate
In the title compound, C(14)H(12)ClN(3)O(2)·H(2)O, the benzene ring and the pyridine rings are oriented at a dihedral angle of 57.73 (12)° and an intramolecular O—H⋯N hydrogen bond generates an S(6) ring. In the crystal, the water molecule forms O—H⋯O and O—H⋯N hydrogen bonds to the organic molec...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006986/ https://www.ncbi.nlm.nih.gov/pubmed/21588074 http://dx.doi.org/10.1107/S1600536810025213 |
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author | Hussain, Abid Shafiq, Zahid Tahir, M. Nawaz Yaqub, Muhammad |
author_facet | Hussain, Abid Shafiq, Zahid Tahir, M. Nawaz Yaqub, Muhammad |
author_sort | Hussain, Abid |
collection | PubMed |
description | In the title compound, C(14)H(12)ClN(3)O(2)·H(2)O, the benzene ring and the pyridine rings are oriented at a dihedral angle of 57.73 (12)° and an intramolecular O—H⋯N hydrogen bond generates an S(6) ring. In the crystal, the water molecule forms O—H⋯O and O—H⋯N hydrogen bonds to the organic molecule, leading to chains containing R (4) (4)(16) loops. In addition, weak aromatic π–π stacking interactions between the centroids of pyridine rings [at distance of 3.864 (2) and 4.013 (2) Å] and C—H⋯π interactions occur. |
format | Text |
id | pubmed-3006986 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30069862010-12-30 N′-[(E)-1-(5-Chloro-2-hydroxyphenyl)ethylidene]pyridine-3-carbohydrazide monohydrate Hussain, Abid Shafiq, Zahid Tahir, M. Nawaz Yaqub, Muhammad Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(12)ClN(3)O(2)·H(2)O, the benzene ring and the pyridine rings are oriented at a dihedral angle of 57.73 (12)° and an intramolecular O—H⋯N hydrogen bond generates an S(6) ring. In the crystal, the water molecule forms O—H⋯O and O—H⋯N hydrogen bonds to the organic molecule, leading to chains containing R (4) (4)(16) loops. In addition, weak aromatic π–π stacking interactions between the centroids of pyridine rings [at distance of 3.864 (2) and 4.013 (2) Å] and C—H⋯π interactions occur. International Union of Crystallography 2010-06-30 /pmc/articles/PMC3006986/ /pubmed/21588074 http://dx.doi.org/10.1107/S1600536810025213 Text en © Hussain et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Hussain, Abid Shafiq, Zahid Tahir, M. Nawaz Yaqub, Muhammad N′-[(E)-1-(5-Chloro-2-hydroxyphenyl)ethylidene]pyridine-3-carbohydrazide monohydrate |
title |
N′-[(E)-1-(5-Chloro-2-hydroxyphenyl)ethylidene]pyridine-3-carbohydrazide monohydrate |
title_full |
N′-[(E)-1-(5-Chloro-2-hydroxyphenyl)ethylidene]pyridine-3-carbohydrazide monohydrate |
title_fullStr |
N′-[(E)-1-(5-Chloro-2-hydroxyphenyl)ethylidene]pyridine-3-carbohydrazide monohydrate |
title_full_unstemmed |
N′-[(E)-1-(5-Chloro-2-hydroxyphenyl)ethylidene]pyridine-3-carbohydrazide monohydrate |
title_short |
N′-[(E)-1-(5-Chloro-2-hydroxyphenyl)ethylidene]pyridine-3-carbohydrazide monohydrate |
title_sort | n′-[(e)-1-(5-chloro-2-hydroxyphenyl)ethylidene]pyridine-3-carbohydrazide monohydrate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006986/ https://www.ncbi.nlm.nih.gov/pubmed/21588074 http://dx.doi.org/10.1107/S1600536810025213 |
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