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3-(4-Fluorophenylsulfinyl)-5-iodo-2-methyl-1-benzofuran
In the title compound, C(15)H(10)FIO(2)S, the O atom and the 4-fluorophenyl group of the 4-fluorophenylsulfinyl substituent are located on opposite sides of the plane through the benzofuran fragment; the 4-fluorophenyl ring is nearly perpendicular to this plane, making a dihedral angle of 83.37 ...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006988/ https://www.ncbi.nlm.nih.gov/pubmed/21588071 http://dx.doi.org/10.1107/S1600536810024931 |
Sumario: | In the title compound, C(15)H(10)FIO(2)S, the O atom and the 4-fluorophenyl group of the 4-fluorophenylsulfinyl substituent are located on opposite sides of the plane through the benzofuran fragment; the 4-fluorophenyl ring is nearly perpendicular to this plane, making a dihedral angle of 83.37 (7)°. The crystal structure is stabilized by weak intermolecular C—H⋯O hydrogen bonds and an I⋯O interaction [I⋯O = 3.255 (2) Å]. The crystal structure also exhibits intermolecular C—F⋯π interactions [3.068 (2) Å], and aromatic π–π interactions between the furan and benzene rings of neighbouring benzofuran fragments [centroid–centroid distance = 3.636 (2) Å]. |
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