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(E)-1-[(2-Hydroxy-1-naphthyl)methylideneamino]imidazolidine-2,4-dione
The title compound, C(14)H(11)N(3)O(3), adopts an E or trans configuration with respect to the C=N bond. In the molecule there is an intramolecular O—H⋯N hydrogen bond involving the hydroxy substituent at the 2-positon of the naphthalene ring and the adjacent methyleneamino N atom. The molecul...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006989/ https://www.ncbi.nlm.nih.gov/pubmed/21587837 http://dx.doi.org/10.1107/S1600536810020118 |
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author | Sheng, Liang-Quan Xu, Hua-Jie Du, Na-Na Jiang, Xue-Yue |
author_facet | Sheng, Liang-Quan Xu, Hua-Jie Du, Na-Na Jiang, Xue-Yue |
author_sort | Sheng, Liang-Quan |
collection | PubMed |
description | The title compound, C(14)H(11)N(3)O(3), adopts an E or trans configuration with respect to the C=N bond. In the molecule there is an intramolecular O—H⋯N hydrogen bond involving the hydroxy substituent at the 2-positon of the naphthalene ring and the adjacent methyleneamino N atom. The molecule is roughly planar, the dihedral angle between the naphthalene and imidazolidine-2,4-dione mean planes being 8.4 (1)°. In the crystal, pairs of N—H⋯O hydrogen bonds link molecules into inversion dimers. These dimers are futher linked via C—H⋯O interactions, forming a three-dimensional network. |
format | Text |
id | pubmed-3006989 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30069892010-12-30 (E)-1-[(2-Hydroxy-1-naphthyl)methylideneamino]imidazolidine-2,4-dione Sheng, Liang-Quan Xu, Hua-Jie Du, Na-Na Jiang, Xue-Yue Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(14)H(11)N(3)O(3), adopts an E or trans configuration with respect to the C=N bond. In the molecule there is an intramolecular O—H⋯N hydrogen bond involving the hydroxy substituent at the 2-positon of the naphthalene ring and the adjacent methyleneamino N atom. The molecule is roughly planar, the dihedral angle between the naphthalene and imidazolidine-2,4-dione mean planes being 8.4 (1)°. In the crystal, pairs of N—H⋯O hydrogen bonds link molecules into inversion dimers. These dimers are futher linked via C—H⋯O interactions, forming a three-dimensional network. International Union of Crystallography 2010-06-09 /pmc/articles/PMC3006989/ /pubmed/21587837 http://dx.doi.org/10.1107/S1600536810020118 Text en © Sheng et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Sheng, Liang-Quan Xu, Hua-Jie Du, Na-Na Jiang, Xue-Yue (E)-1-[(2-Hydroxy-1-naphthyl)methylideneamino]imidazolidine-2,4-dione |
title | (E)-1-[(2-Hydroxy-1-naphthyl)methylideneamino]imidazolidine-2,4-dione |
title_full | (E)-1-[(2-Hydroxy-1-naphthyl)methylideneamino]imidazolidine-2,4-dione |
title_fullStr | (E)-1-[(2-Hydroxy-1-naphthyl)methylideneamino]imidazolidine-2,4-dione |
title_full_unstemmed | (E)-1-[(2-Hydroxy-1-naphthyl)methylideneamino]imidazolidine-2,4-dione |
title_short | (E)-1-[(2-Hydroxy-1-naphthyl)methylideneamino]imidazolidine-2,4-dione |
title_sort | (e)-1-[(2-hydroxy-1-naphthyl)methylideneamino]imidazolidine-2,4-dione |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006989/ https://www.ncbi.nlm.nih.gov/pubmed/21587837 http://dx.doi.org/10.1107/S1600536810020118 |
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