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Diaqua­bis­(4-carb­oxy-2-propyl-1H-imidazole-5-carboxyl­ato-κ(2) N (3),O (4))zinc(II) N,N-dimethyl­formamide disolvate

In the crystal structure of the title compound, [Zn(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)]·2C(3)H(7)NO, the Zn(II) atom is coordinated by two N,O-bidentate 2-propyl-1H-imidazole-4,5-dicarboxyl­ate anions and two water mol­ecules in a distorted octa­hedral environment. The asymmetric unit consists of one Zn...

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Detalles Bibliográficos
Autores principales: Hao, Cheng-Jun, Zhao, Xiao-Jun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006990/
https://www.ncbi.nlm.nih.gov/pubmed/21587728
http://dx.doi.org/10.1107/S1600536810022282
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author Hao, Cheng-Jun
Zhao, Xiao-Jun
author_facet Hao, Cheng-Jun
Zhao, Xiao-Jun
author_sort Hao, Cheng-Jun
collection PubMed
description In the crystal structure of the title compound, [Zn(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)]·2C(3)H(7)NO, the Zn(II) atom is coordinated by two N,O-bidentate 2-propyl-1H-imidazole-4,5-dicarboxyl­ate anions and two water mol­ecules in a distorted octa­hedral environment. The asymmetric unit consists of one Zn(II) atom located on a center of inversion as well as one anion, one water mol­ecule and one additional dimethyl­formamide mol­ecule that occupy general positions. Between the carboxyl and the carboxyl­ate group an intra­molecular hydrogen bond is found in which the hydroxy H atom is disordered. Disorder is also found for the H atoms of one of the three methyl groups. In the crystal structure, additional inter­molecular N—H⋯O and O—H⋯O hydrogen bonding is found.
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spelling pubmed-30069902010-12-30 Diaqua­bis­(4-carb­oxy-2-propyl-1H-imidazole-5-carboxyl­ato-κ(2) N (3),O (4))zinc(II) N,N-dimethyl­formamide disolvate Hao, Cheng-Jun Zhao, Xiao-Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Zn(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)]·2C(3)H(7)NO, the Zn(II) atom is coordinated by two N,O-bidentate 2-propyl-1H-imidazole-4,5-dicarboxyl­ate anions and two water mol­ecules in a distorted octa­hedral environment. The asymmetric unit consists of one Zn(II) atom located on a center of inversion as well as one anion, one water mol­ecule and one additional dimethyl­formamide mol­ecule that occupy general positions. Between the carboxyl and the carboxyl­ate group an intra­molecular hydrogen bond is found in which the hydroxy H atom is disordered. Disorder is also found for the H atoms of one of the three methyl groups. In the crystal structure, additional inter­molecular N—H⋯O and O—H⋯O hydrogen bonding is found. International Union of Crystallography 2010-06-16 /pmc/articles/PMC3006990/ /pubmed/21587728 http://dx.doi.org/10.1107/S1600536810022282 Text en © Hao and Zhao 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hao, Cheng-Jun
Zhao, Xiao-Jun
Diaqua­bis­(4-carb­oxy-2-propyl-1H-imidazole-5-carboxyl­ato-κ(2) N (3),O (4))zinc(II) N,N-dimethyl­formamide disolvate
title Diaqua­bis­(4-carb­oxy-2-propyl-1H-imidazole-5-carboxyl­ato-κ(2) N (3),O (4))zinc(II) N,N-dimethyl­formamide disolvate
title_full Diaqua­bis­(4-carb­oxy-2-propyl-1H-imidazole-5-carboxyl­ato-κ(2) N (3),O (4))zinc(II) N,N-dimethyl­formamide disolvate
title_fullStr Diaqua­bis­(4-carb­oxy-2-propyl-1H-imidazole-5-carboxyl­ato-κ(2) N (3),O (4))zinc(II) N,N-dimethyl­formamide disolvate
title_full_unstemmed Diaqua­bis­(4-carb­oxy-2-propyl-1H-imidazole-5-carboxyl­ato-κ(2) N (3),O (4))zinc(II) N,N-dimethyl­formamide disolvate
title_short Diaqua­bis­(4-carb­oxy-2-propyl-1H-imidazole-5-carboxyl­ato-κ(2) N (3),O (4))zinc(II) N,N-dimethyl­formamide disolvate
title_sort diaqua­bis­(4-carb­oxy-2-propyl-1h-imidazole-5-carboxyl­ato-κ(2) n (3),o (4))zinc(ii) n,n-dimethyl­formamide disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006990/
https://www.ncbi.nlm.nih.gov/pubmed/21587728
http://dx.doi.org/10.1107/S1600536810022282
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