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Diaquabis(4-carboxy-2-propyl-1H-imidazole-5-carboxylato-κ(2) N (3),O (4))zinc(II) N,N-dimethylformamide disolvate
In the crystal structure of the title compound, [Zn(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)]·2C(3)H(7)NO, the Zn(II) atom is coordinated by two N,O-bidentate 2-propyl-1H-imidazole-4,5-dicarboxylate anions and two water molecules in a distorted octahedral environment. The asymmetric unit consists of one Zn...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006990/ https://www.ncbi.nlm.nih.gov/pubmed/21587728 http://dx.doi.org/10.1107/S1600536810022282 |
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author | Hao, Cheng-Jun Zhao, Xiao-Jun |
author_facet | Hao, Cheng-Jun Zhao, Xiao-Jun |
author_sort | Hao, Cheng-Jun |
collection | PubMed |
description | In the crystal structure of the title compound, [Zn(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)]·2C(3)H(7)NO, the Zn(II) atom is coordinated by two N,O-bidentate 2-propyl-1H-imidazole-4,5-dicarboxylate anions and two water molecules in a distorted octahedral environment. The asymmetric unit consists of one Zn(II) atom located on a center of inversion as well as one anion, one water molecule and one additional dimethylformamide molecule that occupy general positions. Between the carboxyl and the carboxylate group an intramolecular hydrogen bond is found in which the hydroxy H atom is disordered. Disorder is also found for the H atoms of one of the three methyl groups. In the crystal structure, additional intermolecular N—H⋯O and O—H⋯O hydrogen bonding is found. |
format | Text |
id | pubmed-3006990 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30069902010-12-30 Diaquabis(4-carboxy-2-propyl-1H-imidazole-5-carboxylato-κ(2) N (3),O (4))zinc(II) N,N-dimethylformamide disolvate Hao, Cheng-Jun Zhao, Xiao-Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Zn(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)]·2C(3)H(7)NO, the Zn(II) atom is coordinated by two N,O-bidentate 2-propyl-1H-imidazole-4,5-dicarboxylate anions and two water molecules in a distorted octahedral environment. The asymmetric unit consists of one Zn(II) atom located on a center of inversion as well as one anion, one water molecule and one additional dimethylformamide molecule that occupy general positions. Between the carboxyl and the carboxylate group an intramolecular hydrogen bond is found in which the hydroxy H atom is disordered. Disorder is also found for the H atoms of one of the three methyl groups. In the crystal structure, additional intermolecular N—H⋯O and O—H⋯O hydrogen bonding is found. International Union of Crystallography 2010-06-16 /pmc/articles/PMC3006990/ /pubmed/21587728 http://dx.doi.org/10.1107/S1600536810022282 Text en © Hao and Zhao 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Hao, Cheng-Jun Zhao, Xiao-Jun Diaquabis(4-carboxy-2-propyl-1H-imidazole-5-carboxylato-κ(2) N (3),O (4))zinc(II) N,N-dimethylformamide disolvate |
title | Diaquabis(4-carboxy-2-propyl-1H-imidazole-5-carboxylato-κ(2)
N
(3),O
(4))zinc(II) N,N-dimethylformamide disolvate |
title_full | Diaquabis(4-carboxy-2-propyl-1H-imidazole-5-carboxylato-κ(2)
N
(3),O
(4))zinc(II) N,N-dimethylformamide disolvate |
title_fullStr | Diaquabis(4-carboxy-2-propyl-1H-imidazole-5-carboxylato-κ(2)
N
(3),O
(4))zinc(II) N,N-dimethylformamide disolvate |
title_full_unstemmed | Diaquabis(4-carboxy-2-propyl-1H-imidazole-5-carboxylato-κ(2)
N
(3),O
(4))zinc(II) N,N-dimethylformamide disolvate |
title_short | Diaquabis(4-carboxy-2-propyl-1H-imidazole-5-carboxylato-κ(2)
N
(3),O
(4))zinc(II) N,N-dimethylformamide disolvate |
title_sort | diaquabis(4-carboxy-2-propyl-1h-imidazole-5-carboxylato-κ(2)
n
(3),o
(4))zinc(ii) n,n-dimethylformamide disolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006990/ https://www.ncbi.nlm.nih.gov/pubmed/21587728 http://dx.doi.org/10.1107/S1600536810022282 |
work_keys_str_mv | AT haochengjun diaquabis4carboxy2propyl1himidazole5carboxylatok2n3o4zinciinndimethylformamidedisolvate AT zhaoxiaojun diaquabis4carboxy2propyl1himidazole5carboxylatok2n3o4zinciinndimethylformamidedisolvate |