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(2-{[1,1-Bis(hydroxymethyl)-2-oxidoethyl]iminomethyl}-4-chlorophenolato-κ(3) O,N,O′)dibutyltin(IV)
In the title compound, [Sn(C(4)H(9))(2)(C(11)H(12)BrNO(4))], the Schiff base ligand chelates to the Sn(IV) atom through the two deprotonated hydroxy groups, as well as through the N atom, to confer an overall cis-C(2)SnNO(2) trigonal-bipyramidal geometry at the Sn(IV) atom [C—Sn—C = 129.92 (9)°]. T...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006995/ https://www.ncbi.nlm.nih.gov/pubmed/21587717 http://dx.doi.org/10.1107/S1600536810021872 |
| Sumario: | In the title compound, [Sn(C(4)H(9))(2)(C(11)H(12)BrNO(4))], the Schiff base ligand chelates to the Sn(IV) atom through the two deprotonated hydroxy groups, as well as through the N atom, to confer an overall cis-C(2)SnNO(2) trigonal-bipyramidal geometry at the Sn(IV) atom [C—Sn—C = 129.92 (9)°]. The remaining methylenehydroxy groups engage in O—H⋯O hydrogen bonding with the O atoms of adjacent molecules, leading to infinite supramolecular chains propagating in [001]. |
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