(2-{[1,1-Bis(hy­droxy­meth­yl)-2-oxidoeth­yl]imino­meth­yl}-4-chloro­phenolato-κ(3) O,N,O′)dibutyl­tin(IV)

In the title compound, [Sn(C(4)H(9))(2)(C(11)H(12)BrNO(4))], the Schiff base ligand chelates to the Sn(IV) atom through the two deprotonated hy­droxy groups, as well as through the N atom, to confer an overall cis-C(2)SnNO(2) trigonal-bipyramidal geometry at the Sn(IV) atom [C—Sn—C = 129.92 (9)°]. T...

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Detalles Bibliográficos
Autores principales: Lee, See Mun, Mohd Ali, Hapipah, Lo, Kong Mun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006995/
https://www.ncbi.nlm.nih.gov/pubmed/21587717
http://dx.doi.org/10.1107/S1600536810021872
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author Lee, See Mun
Mohd Ali, Hapipah
Lo, Kong Mun
author_facet Lee, See Mun
Mohd Ali, Hapipah
Lo, Kong Mun
author_sort Lee, See Mun
collection PubMed
description In the title compound, [Sn(C(4)H(9))(2)(C(11)H(12)BrNO(4))], the Schiff base ligand chelates to the Sn(IV) atom through the two deprotonated hy­droxy groups, as well as through the N atom, to confer an overall cis-C(2)SnNO(2) trigonal-bipyramidal geometry at the Sn(IV) atom [C—Sn—C = 129.92 (9)°]. The remaining methyl­enehy­droxy groups engage in O—H⋯O hydrogen bonding with the O atoms of adjacent mol­ecules, leading to infinite supra­molecular chains propagating in [001].
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spelling pubmed-30069952010-12-30 (2-{[1,1-Bis(hy­droxy­meth­yl)-2-oxidoeth­yl]imino­meth­yl}-4-chloro­phenolato-κ(3) O,N,O′)dibutyl­tin(IV) Lee, See Mun Mohd Ali, Hapipah Lo, Kong Mun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Sn(C(4)H(9))(2)(C(11)H(12)BrNO(4))], the Schiff base ligand chelates to the Sn(IV) atom through the two deprotonated hy­droxy groups, as well as through the N atom, to confer an overall cis-C(2)SnNO(2) trigonal-bipyramidal geometry at the Sn(IV) atom [C—Sn—C = 129.92 (9)°]. The remaining methyl­enehy­droxy groups engage in O—H⋯O hydrogen bonding with the O atoms of adjacent mol­ecules, leading to infinite supra­molecular chains propagating in [001]. International Union of Crystallography 2010-06-16 /pmc/articles/PMC3006995/ /pubmed/21587717 http://dx.doi.org/10.1107/S1600536810021872 Text en © Lee et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lee, See Mun
Mohd Ali, Hapipah
Lo, Kong Mun
(2-{[1,1-Bis(hy­droxy­meth­yl)-2-oxidoeth­yl]imino­meth­yl}-4-chloro­phenolato-κ(3) O,N,O′)dibutyl­tin(IV)
title (2-{[1,1-Bis(hy­droxy­meth­yl)-2-oxidoeth­yl]imino­meth­yl}-4-chloro­phenolato-κ(3) O,N,O′)dibutyl­tin(IV)
title_full (2-{[1,1-Bis(hy­droxy­meth­yl)-2-oxidoeth­yl]imino­meth­yl}-4-chloro­phenolato-κ(3) O,N,O′)dibutyl­tin(IV)
title_fullStr (2-{[1,1-Bis(hy­droxy­meth­yl)-2-oxidoeth­yl]imino­meth­yl}-4-chloro­phenolato-κ(3) O,N,O′)dibutyl­tin(IV)
title_full_unstemmed (2-{[1,1-Bis(hy­droxy­meth­yl)-2-oxidoeth­yl]imino­meth­yl}-4-chloro­phenolato-κ(3) O,N,O′)dibutyl­tin(IV)
title_short (2-{[1,1-Bis(hy­droxy­meth­yl)-2-oxidoeth­yl]imino­meth­yl}-4-chloro­phenolato-κ(3) O,N,O′)dibutyl­tin(IV)
title_sort (2-{[1,1-bis(hy­droxy­meth­yl)-2-oxidoeth­yl]imino­meth­yl}-4-chloro­phenolato-κ(3) o,n,o′)dibutyl­tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006995/
https://www.ncbi.nlm.nih.gov/pubmed/21587717
http://dx.doi.org/10.1107/S1600536810021872
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AT lokongmun 211bishydroxymethyl2oxidoethyliminomethyl4chlorophenolatok3onodibutyltiniv

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