(2E)-1-(6-Chloro-2-methyl-4-phenyl­quinolin-3-yl)-3-phenyl­prop-2-en-1-one

In the title compound, C(25)H(18)ClNO, the conformation about the C=C double bond is E. Significant twists are evident in the mol­ecule, with the benzene ring forming a dihedral angle of 53.92 (11)° with the quinolinyl residue. Further, the chalcone residue is approximately perpendicular to the quin...

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Autores principales: Viji, A. J., Sarveswari, S., Vijayakumar, V., Tan, Kong Wai, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006996/
https://www.ncbi.nlm.nih.gov/pubmed/21587992
http://dx.doi.org/10.1107/S160053681002386X
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author Viji, A. J.
Sarveswari, S.
Vijayakumar, V.
Tan, Kong Wai
Tiekink, Edward R. T.
author_facet Viji, A. J.
Sarveswari, S.
Vijayakumar, V.
Tan, Kong Wai
Tiekink, Edward R. T.
author_sort Viji, A. J.
collection PubMed
description In the title compound, C(25)H(18)ClNO, the conformation about the C=C double bond is E. Significant twists are evident in the mol­ecule, with the benzene ring forming a dihedral angle of 53.92 (11)° with the quinolinyl residue. Further, the chalcone residue is approximately perpendicular to the quinolinyl residue [C(q)—C(q)—C(c)—O(c) torsion angle = −104.5 (3)°, where q = quinolinyl and c = chalcone]. In the crystal, the presence of C—H⋯O and C—H⋯π inter­actions leads to supra­molecular layers lying parallel to ([Image: see text]02).
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spelling pubmed-30069962010-12-30 (2E)-1-(6-Chloro-2-methyl-4-phenyl­quinolin-3-yl)-3-phenyl­prop-2-en-1-one Viji, A. J. Sarveswari, S. Vijayakumar, V. Tan, Kong Wai Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(25)H(18)ClNO, the conformation about the C=C double bond is E. Significant twists are evident in the mol­ecule, with the benzene ring forming a dihedral angle of 53.92 (11)° with the quinolinyl residue. Further, the chalcone residue is approximately perpendicular to the quinolinyl residue [C(q)—C(q)—C(c)—O(c) torsion angle = −104.5 (3)°, where q = quinolinyl and c = chalcone]. In the crystal, the presence of C—H⋯O and C—H⋯π inter­actions leads to supra­molecular layers lying parallel to ([Image: see text]02). International Union of Crystallography 2010-06-26 /pmc/articles/PMC3006996/ /pubmed/21587992 http://dx.doi.org/10.1107/S160053681002386X Text en © Viji et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Viji, A. J.
Sarveswari, S.
Vijayakumar, V.
Tan, Kong Wai
Tiekink, Edward R. T.
(2E)-1-(6-Chloro-2-methyl-4-phenyl­quinolin-3-yl)-3-phenyl­prop-2-en-1-one
title (2E)-1-(6-Chloro-2-methyl-4-phenyl­quinolin-3-yl)-3-phenyl­prop-2-en-1-one
title_full (2E)-1-(6-Chloro-2-methyl-4-phenyl­quinolin-3-yl)-3-phenyl­prop-2-en-1-one
title_fullStr (2E)-1-(6-Chloro-2-methyl-4-phenyl­quinolin-3-yl)-3-phenyl­prop-2-en-1-one
title_full_unstemmed (2E)-1-(6-Chloro-2-methyl-4-phenyl­quinolin-3-yl)-3-phenyl­prop-2-en-1-one
title_short (2E)-1-(6-Chloro-2-methyl-4-phenyl­quinolin-3-yl)-3-phenyl­prop-2-en-1-one
title_sort (2e)-1-(6-chloro-2-methyl-4-phenyl­quinolin-3-yl)-3-phenyl­prop-2-en-1-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006996/
https://www.ncbi.nlm.nih.gov/pubmed/21587992
http://dx.doi.org/10.1107/S160053681002386X
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AT vijayakumarv 2e16chloro2methyl4phenylquinolin3yl3phenylprop2en1one
AT tankongwai 2e16chloro2methyl4phenylquinolin3yl3phenylprop2en1one
AT tiekinkedwardrt 2e16chloro2methyl4phenylquinolin3yl3phenylprop2en1one

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