3-{2-[2-(Diphenyl­methyl­ene)hydrazin­yl]thia­zol-4-yl}-2H-chromen-2-one

In the title compound, C(25)H(17)N(3)O(2)S, the coumarin ring system is essentially planar with a maximum deviation of 0.019 (2) Å. A weak intra­molecular C—H⋯O hydrogen bond stabilizes the mol­ecular structure, so that the coumarin plane is approximately coplanar with the thia­zole ring, making a d...

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Detalles Bibliográficos
Autores principales: Arshad, Afsheen, Osman, Hasnah, Chan, Kit Lam, Yeap, Chin Sing, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007000/
https://www.ncbi.nlm.nih.gov/pubmed/21587999
http://dx.doi.org/10.1107/S1600536810023627
Descripción
Sumario:In the title compound, C(25)H(17)N(3)O(2)S, the coumarin ring system is essentially planar with a maximum deviation of 0.019 (2) Å. A weak intra­molecular C—H⋯O hydrogen bond stabilizes the mol­ecular structure, so that the coumarin plane is approximately coplanar with the thia­zole ring, making a dihedral angle of 2.5 (10)°. The two phenyl rings are nearly perpendicular to each other, with a dihedral angle of 81.44 (12)°. In the crystal structure, the mol­ecules are linked into an infinite chain along the b axis by inter­molecular C—H⋯O hydrogen bonds. Weak C—H⋯π inter­actions are observed between the chains.

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