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(Z)-Ethyl 2-oxo-3-(1,2-dihydroquinolin-2-yl­idene)propano­ate

Both independent mol­ecules in the asymmetric unit of the tautomeric title compound, C(14)H(13)NO(3), a synthetic product obtained from 2-lithio­methyl­quinoline and diethyl oxalate, crystallize in the enaminone form with a Z configuration around the double bond. Intra­molecular N—H⋯O hydrogen bonds...

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Detalles Bibliográficos
Autores principales: Valkonen, Arto, Kolehmainen, Erkki, Ośmiałowski, Borys, Gawinecki, Ryszard
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007001/
https://www.ncbi.nlm.nih.gov/pubmed/21587963
http://dx.doi.org/10.1107/S160053681002324X
Descripción
Sumario:Both independent mol­ecules in the asymmetric unit of the tautomeric title compound, C(14)H(13)NO(3), a synthetic product obtained from 2-lithio­methyl­quinoline and diethyl oxalate, crystallize in the enaminone form with a Z configuration around the double bond. Intra­molecular N—H⋯O hydrogen bonds occur, generating an S(6) graph-set motif. In the crystal, weak inter­molecular C—H⋯O and π–π stacking inter­actions [centroid–centroid distances = 3.7020 (14)–3.7429 (13)Å] define a three-dimensional supra­molecular network.