Bis[μ-4-(dimethyl­amino)­benzoato]-κ(3) O,O′:O;κ(3) O:O,O′-bis­{aqua­[4-(dimethyl­amino)­benzoato-κ(2) O,O′](nicotinamide-κN (1))cadmium(II)}

In the centrosymmetric dimeric Cd(II) title compound, [Cd(2)(C(9)H(10)NO(2))(4)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], each seven-coordin­ated Cd(II) atom is chelated by the carboxyl­ate groups of the two 4-(dimethyl­amino)­benzoate (DMAB) anions; the two monomeric units are bridged through the two O atoms o...

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Detalles Bibliográficos
Autores principales: Hökelek, Tuncer, Süzen, Yasemin, Tercan, Barış, Aybirdi, Özgür, Necefoğlu, Hacali
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007006/
https://www.ncbi.nlm.nih.gov/pubmed/21587709
http://dx.doi.org/10.1107/S160053681002163X
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author Hökelek, Tuncer
Süzen, Yasemin
Tercan, Barış
Aybirdi, Özgür
Necefoğlu, Hacali
author_facet Hökelek, Tuncer
Süzen, Yasemin
Tercan, Barış
Aybirdi, Özgür
Necefoğlu, Hacali
author_sort Hökelek, Tuncer
collection PubMed
description In the centrosymmetric dimeric Cd(II) title compound, [Cd(2)(C(9)H(10)NO(2))(4)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], each seven-coordin­ated Cd(II) atom is chelated by the carboxyl­ate groups of the two 4-(dimethyl­amino)­benzoate (DMAB) anions; the two monomeric units are bridged through the two O atoms of the two carboxyl groups. In the crystal structure, inter­molecular O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network. π–π contacts between the pyridine rings [centroid–centroid distance = 3.974 (1) Å] may further stabilize the structure. Weak C—H⋯π inter­actions are also observed.
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spelling pubmed-30070062010-12-30 Bis[μ-4-(dimethyl­amino)­benzoato]-κ(3) O,O′:O;κ(3) O:O,O′-bis­{aqua­[4-(dimethyl­amino)­benzoato-κ(2) O,O′](nicotinamide-κN (1))cadmium(II)} Hökelek, Tuncer Süzen, Yasemin Tercan, Barış Aybirdi, Özgür Necefoğlu, Hacali Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric dimeric Cd(II) title compound, [Cd(2)(C(9)H(10)NO(2))(4)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], each seven-coordin­ated Cd(II) atom is chelated by the carboxyl­ate groups of the two 4-(dimethyl­amino)­benzoate (DMAB) anions; the two monomeric units are bridged through the two O atoms of the two carboxyl groups. In the crystal structure, inter­molecular O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network. π–π contacts between the pyridine rings [centroid–centroid distance = 3.974 (1) Å] may further stabilize the structure. Weak C—H⋯π inter­actions are also observed. International Union of Crystallography 2010-06-16 /pmc/articles/PMC3007006/ /pubmed/21587709 http://dx.doi.org/10.1107/S160053681002163X Text en © Hökelek et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hökelek, Tuncer
Süzen, Yasemin
Tercan, Barış
Aybirdi, Özgür
Necefoğlu, Hacali
Bis[μ-4-(dimethyl­amino)­benzoato]-κ(3) O,O′:O;κ(3) O:O,O′-bis­{aqua­[4-(dimethyl­amino)­benzoato-κ(2) O,O′](nicotinamide-κN (1))cadmium(II)}
title Bis[μ-4-(dimethyl­amino)­benzoato]-κ(3) O,O′:O;κ(3) O:O,O′-bis­{aqua­[4-(dimethyl­amino)­benzoato-κ(2) O,O′](nicotinamide-κN (1))cadmium(II)}
title_full Bis[μ-4-(dimethyl­amino)­benzoato]-κ(3) O,O′:O;κ(3) O:O,O′-bis­{aqua­[4-(dimethyl­amino)­benzoato-κ(2) O,O′](nicotinamide-κN (1))cadmium(II)}
title_fullStr Bis[μ-4-(dimethyl­amino)­benzoato]-κ(3) O,O′:O;κ(3) O:O,O′-bis­{aqua­[4-(dimethyl­amino)­benzoato-κ(2) O,O′](nicotinamide-κN (1))cadmium(II)}
title_full_unstemmed Bis[μ-4-(dimethyl­amino)­benzoato]-κ(3) O,O′:O;κ(3) O:O,O′-bis­{aqua­[4-(dimethyl­amino)­benzoato-κ(2) O,O′](nicotinamide-κN (1))cadmium(II)}
title_short Bis[μ-4-(dimethyl­amino)­benzoato]-κ(3) O,O′:O;κ(3) O:O,O′-bis­{aqua­[4-(dimethyl­amino)­benzoato-κ(2) O,O′](nicotinamide-κN (1))cadmium(II)}
title_sort bis[μ-4-(dimethyl­amino)­benzoato]-κ(3) o,o′:o;κ(3) o:o,o′-bis­{aqua­[4-(dimethyl­amino)­benzoato-κ(2) o,o′](nicotinamide-κn (1))cadmium(ii)}
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007006/
https://www.ncbi.nlm.nih.gov/pubmed/21587709
http://dx.doi.org/10.1107/S160053681002163X
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