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Bis(2-amino-4-methyl­pyridinium) trans-diaqua­bis­(pyrazine-2,3-dicarboxyl­ato)cuprate(II) hexa­hydrate

The title compound, (C(6)H(9)N(2))(2)[Cu(C(6)H(2)N(2)O(4))(2)(H(2)O)(2)]·6H(2)O, consists of a mononuclear trans-[Cu(pzdc)(2)(H(2)O)(2)](2−) dianion (pzdc is pyrazine-2,3-dicarboxyl­ate) and two [ampyH](+) cations (ampy is 2-amino-4-methyl­pyridine) with six water mol­ecules of solvation. The Cu(II)...

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Detalles Bibliográficos
Autores principales: Eshtiagh-Hosseini, Hossein, Gschwind, Fabienne, Alfi, Nafiseh, Mirzaei, Masoud
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007013/
https://www.ncbi.nlm.nih.gov/pubmed/21587740
http://dx.doi.org/10.1107/S1600536810023081
Descripción
Sumario:The title compound, (C(6)H(9)N(2))(2)[Cu(C(6)H(2)N(2)O(4))(2)(H(2)O)(2)]·6H(2)O, consists of a mononuclear trans-[Cu(pzdc)(2)(H(2)O)(2)](2−) dianion (pzdc is pyrazine-2,3-dicarboxyl­ate) and two [ampyH](+) cations (ampy is 2-amino-4-methyl­pyridine) with six water mol­ecules of solvation. The Cu(II) atom is hexa­coordinated by two pzdc groups and two water mol­ecules. The coordinated water mol­ecules are in trans-diaxial positions and the pzdc dianion acts as a bidentate ligand through an O atom of the carboxyl­ate group and the N atom of the pyrazine ring. There are diverse hydrogen-bonding inter­actions, such as N—H⋯O and O—H⋯O contacts, which lead to the formation of a three-dimensional supra­molecular architecture.