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Bis(2-amino-4-methylpyridinium) trans-diaquabis(pyrazine-2,3-dicarboxylato)cuprate(II) hexahydrate
The title compound, (C(6)H(9)N(2))(2)[Cu(C(6)H(2)N(2)O(4))(2)(H(2)O)(2)]·6H(2)O, consists of a mononuclear trans-[Cu(pzdc)(2)(H(2)O)(2)](2−) dianion (pzdc is pyrazine-2,3-dicarboxylate) and two [ampyH](+) cations (ampy is 2-amino-4-methylpyridine) with six water molecules of solvation. The Cu(II)...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007013/ https://www.ncbi.nlm.nih.gov/pubmed/21587740 http://dx.doi.org/10.1107/S1600536810023081 |
Sumario: | The title compound, (C(6)H(9)N(2))(2)[Cu(C(6)H(2)N(2)O(4))(2)(H(2)O)(2)]·6H(2)O, consists of a mononuclear trans-[Cu(pzdc)(2)(H(2)O)(2)](2−) dianion (pzdc is pyrazine-2,3-dicarboxylate) and two [ampyH](+) cations (ampy is 2-amino-4-methylpyridine) with six water molecules of solvation. The Cu(II) atom is hexacoordinated by two pzdc groups and two water molecules. The coordinated water molecules are in trans-diaxial positions and the pzdc dianion acts as a bidentate ligand through an O atom of the carboxylate group and the N atom of the pyrazine ring. There are diverse hydrogen-bonding interactions, such as N—H⋯O and O—H⋯O contacts, which lead to the formation of a three-dimensional supramolecular architecture. |
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