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Bis(2-amino-4-methyl­pyridinium) trans-diaqua­bis­(pyrazine-2,3-dicarboxyl­ato)cuprate(II) hexa­hydrate

The title compound, (C(6)H(9)N(2))(2)[Cu(C(6)H(2)N(2)O(4))(2)(H(2)O)(2)]·6H(2)O, consists of a mononuclear trans-[Cu(pzdc)(2)(H(2)O)(2)](2−) dianion (pzdc is pyrazine-2,3-dicarboxyl­ate) and two [ampyH](+) cations (ampy is 2-amino-4-methyl­pyridine) with six water mol­ecules of solvation. The Cu(II)...

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Autores principales: Eshtiagh-Hosseini, Hossein, Gschwind, Fabienne, Alfi, Nafiseh, Mirzaei, Masoud
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007013/
https://www.ncbi.nlm.nih.gov/pubmed/21587740
http://dx.doi.org/10.1107/S1600536810023081
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author Eshtiagh-Hosseini, Hossein
Gschwind, Fabienne
Alfi, Nafiseh
Mirzaei, Masoud
author_facet Eshtiagh-Hosseini, Hossein
Gschwind, Fabienne
Alfi, Nafiseh
Mirzaei, Masoud
author_sort Eshtiagh-Hosseini, Hossein
collection PubMed
description The title compound, (C(6)H(9)N(2))(2)[Cu(C(6)H(2)N(2)O(4))(2)(H(2)O)(2)]·6H(2)O, consists of a mononuclear trans-[Cu(pzdc)(2)(H(2)O)(2)](2−) dianion (pzdc is pyrazine-2,3-dicarboxyl­ate) and two [ampyH](+) cations (ampy is 2-amino-4-methyl­pyridine) with six water mol­ecules of solvation. The Cu(II) atom is hexa­coordinated by two pzdc groups and two water mol­ecules. The coordinated water mol­ecules are in trans-diaxial positions and the pzdc dianion acts as a bidentate ligand through an O atom of the carboxyl­ate group and the N atom of the pyrazine ring. There are diverse hydrogen-bonding inter­actions, such as N—H⋯O and O—H⋯O contacts, which lead to the formation of a three-dimensional supra­molecular architecture.
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spelling pubmed-30070132010-12-30 Bis(2-amino-4-methyl­pyridinium) trans-diaqua­bis­(pyrazine-2,3-dicarboxyl­ato)cuprate(II) hexa­hydrate Eshtiagh-Hosseini, Hossein Gschwind, Fabienne Alfi, Nafiseh Mirzaei, Masoud Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(6)H(9)N(2))(2)[Cu(C(6)H(2)N(2)O(4))(2)(H(2)O)(2)]·6H(2)O, consists of a mononuclear trans-[Cu(pzdc)(2)(H(2)O)(2)](2−) dianion (pzdc is pyrazine-2,3-dicarboxyl­ate) and two [ampyH](+) cations (ampy is 2-amino-4-methyl­pyridine) with six water mol­ecules of solvation. The Cu(II) atom is hexa­coordinated by two pzdc groups and two water mol­ecules. The coordinated water mol­ecules are in trans-diaxial positions and the pzdc dianion acts as a bidentate ligand through an O atom of the carboxyl­ate group and the N atom of the pyrazine ring. There are diverse hydrogen-bonding inter­actions, such as N—H⋯O and O—H⋯O contacts, which lead to the formation of a three-dimensional supra­molecular architecture. International Union of Crystallography 2010-06-23 /pmc/articles/PMC3007013/ /pubmed/21587740 http://dx.doi.org/10.1107/S1600536810023081 Text en © Eshtiagh-Hosseini et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Eshtiagh-Hosseini, Hossein
Gschwind, Fabienne
Alfi, Nafiseh
Mirzaei, Masoud
Bis(2-amino-4-methyl­pyridinium) trans-diaqua­bis­(pyrazine-2,3-dicarboxyl­ato)cuprate(II) hexa­hydrate
title Bis(2-amino-4-methyl­pyridinium) trans-diaqua­bis­(pyrazine-2,3-dicarboxyl­ato)cuprate(II) hexa­hydrate
title_full Bis(2-amino-4-methyl­pyridinium) trans-diaqua­bis­(pyrazine-2,3-dicarboxyl­ato)cuprate(II) hexa­hydrate
title_fullStr Bis(2-amino-4-methyl­pyridinium) trans-diaqua­bis­(pyrazine-2,3-dicarboxyl­ato)cuprate(II) hexa­hydrate
title_full_unstemmed Bis(2-amino-4-methyl­pyridinium) trans-diaqua­bis­(pyrazine-2,3-dicarboxyl­ato)cuprate(II) hexa­hydrate
title_short Bis(2-amino-4-methyl­pyridinium) trans-diaqua­bis­(pyrazine-2,3-dicarboxyl­ato)cuprate(II) hexa­hydrate
title_sort bis(2-amino-4-methyl­pyridinium) trans-diaqua­bis­(pyrazine-2,3-dicarboxyl­ato)cuprate(ii) hexa­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007013/
https://www.ncbi.nlm.nih.gov/pubmed/21587740
http://dx.doi.org/10.1107/S1600536810023081
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