2,6-Di(pyrrolidin-1-yl)pyridinium chloride monohydrate

In the organic cation of the title compound, C(13)H(20)N(3) (+)·Cl(−)·H(2)O, the two pyrrolidine rings adopt twisted conformations. The pyridine ring makes dihedral angles of 14.57 (6) and 23.96 (6)° with the mean planes of the pyrrolidine rings. In the crystal structure, pairs of bifurcated inter­m...

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Detalles Bibliográficos
Autores principales: Al-Dajani, Mohammad T. M., Abdallah, Hassan H., Mohamed, Nornisah, Goh, Jia Hao, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007020/
https://www.ncbi.nlm.nih.gov/pubmed/21588023
http://dx.doi.org/10.1107/S160053681002427X
Descripción
Sumario:In the organic cation of the title compound, C(13)H(20)N(3) (+)·Cl(−)·H(2)O, the two pyrrolidine rings adopt twisted conformations. The pyridine ring makes dihedral angles of 14.57 (6) and 23.96 (6)° with the mean planes of the pyrrolidine rings. In the crystal structure, pairs of bifurcated inter­molecular O—H⋯Cl hydrogen bonds link the water mol­ecules and chloride anions into an R (4) (4)(8) ring motif. Inter­molecular N—H⋯Cl, C—H⋯Cl and C—H⋯O hydrogen bonds further inter­connect these rings with the organic cations into a two-dimensional network parallel to the bc plane.

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