2,6-Di(pyrrolidin-1-yl)pyridinium chloride monohydrate

In the organic cation of the title compound, C(13)H(20)N(3) (+)·Cl(−)·H(2)O, the two pyrrolidine rings adopt twisted conformations. The pyridine ring makes dihedral angles of 14.57 (6) and 23.96 (6)° with the mean planes of the pyrrolidine rings. In the crystal structure, pairs of bifurcated inter­m...

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Autores principales: Al-Dajani, Mohammad T. M., Abdallah, Hassan H., Mohamed, Nornisah, Goh, Jia Hao, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007020/
https://www.ncbi.nlm.nih.gov/pubmed/21588023
http://dx.doi.org/10.1107/S160053681002427X
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author Al-Dajani, Mohammad T. M.
Abdallah, Hassan H.
Mohamed, Nornisah
Goh, Jia Hao
Fun, Hoong-Kun
author_facet Al-Dajani, Mohammad T. M.
Abdallah, Hassan H.
Mohamed, Nornisah
Goh, Jia Hao
Fun, Hoong-Kun
author_sort Al-Dajani, Mohammad T. M.
collection PubMed
description In the organic cation of the title compound, C(13)H(20)N(3) (+)·Cl(−)·H(2)O, the two pyrrolidine rings adopt twisted conformations. The pyridine ring makes dihedral angles of 14.57 (6) and 23.96 (6)° with the mean planes of the pyrrolidine rings. In the crystal structure, pairs of bifurcated inter­molecular O—H⋯Cl hydrogen bonds link the water mol­ecules and chloride anions into an R (4) (4)(8) ring motif. Inter­molecular N—H⋯Cl, C—H⋯Cl and C—H⋯O hydrogen bonds further inter­connect these rings with the organic cations into a two-dimensional network parallel to the bc plane.
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spelling pubmed-30070202010-12-30 2,6-Di(pyrrolidin-1-yl)pyridinium chloride monohydrate Al-Dajani, Mohammad T. M. Abdallah, Hassan H. Mohamed, Nornisah Goh, Jia Hao Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the organic cation of the title compound, C(13)H(20)N(3) (+)·Cl(−)·H(2)O, the two pyrrolidine rings adopt twisted conformations. The pyridine ring makes dihedral angles of 14.57 (6) and 23.96 (6)° with the mean planes of the pyrrolidine rings. In the crystal structure, pairs of bifurcated inter­molecular O—H⋯Cl hydrogen bonds link the water mol­ecules and chloride anions into an R (4) (4)(8) ring motif. Inter­molecular N—H⋯Cl, C—H⋯Cl and C—H⋯O hydrogen bonds further inter­connect these rings with the organic cations into a two-dimensional network parallel to the bc plane. International Union of Crystallography 2010-06-26 /pmc/articles/PMC3007020/ /pubmed/21588023 http://dx.doi.org/10.1107/S160053681002427X Text en © Al-Dajani et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Al-Dajani, Mohammad T. M.
Abdallah, Hassan H.
Mohamed, Nornisah
Goh, Jia Hao
Fun, Hoong-Kun
2,6-Di(pyrrolidin-1-yl)pyridinium chloride monohydrate
title 2,6-Di(pyrrolidin-1-yl)pyridinium chloride monohydrate
title_full 2,6-Di(pyrrolidin-1-yl)pyridinium chloride monohydrate
title_fullStr 2,6-Di(pyrrolidin-1-yl)pyridinium chloride monohydrate
title_full_unstemmed 2,6-Di(pyrrolidin-1-yl)pyridinium chloride monohydrate
title_short 2,6-Di(pyrrolidin-1-yl)pyridinium chloride monohydrate
title_sort 2,6-di(pyrrolidin-1-yl)pyridinium chloride monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007020/
https://www.ncbi.nlm.nih.gov/pubmed/21588023
http://dx.doi.org/10.1107/S160053681002427X
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