1-[(E)-4-(5-Bromo-1H-indol-3-yl)-1-methyl-2,5,6,7-tetra­hydro-1H-azepin-2-yl­idene]propan-2-one

In the title compound, C(18)H(19)BrN(2)O, the seven-membered azepine ring adopts a twist-boat conformation: the bond angles about the azepine N atom are indicative of sp (2) hybridization. The dihedral angle between the plane of the carbon–carbon double bond of the enone unit and the mean plane of t...

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Detalles Bibliográficos
Autores principales: Helliwell, Madeleine, Aghazadeh, Masomeh, Baradarani, Mehdi M., Joule, John A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007022/
https://www.ncbi.nlm.nih.gov/pubmed/21587781
http://dx.doi.org/10.1107/S1600536810019975
Descripción
Sumario:In the title compound, C(18)H(19)BrN(2)O, the seven-membered azepine ring adopts a twist-boat conformation: the bond angles about the azepine N atom are indicative of sp (2) hybridization. The dihedral angle between the plane of the carbon–carbon double bond of the enone unit and the mean plane of the indole ring is 27.8 (1)°. In the crystal, an N—H⋯O hydrogen bond links the mol­ecules into chains along the b axis.

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