μ(4)-Sulfido-bis­{(μ-2-furyl­methane­thiol­ato)bis­[tricarbonyl­iron](Fe—Fe)}

The title compound, [Fe(4)(C(5)H(5)OS)(2)S(CO)(12)], was prepared by the direct reaction of Fe(3)(CO)(12) and 2-furyl­methane­thiol in tetra­hydro­furan. Desulfurization took place readily to form an Fe(4)S(3) cluster. The mol­ecule consists of two similar [(μ-2-C(4)H(3)O—CH(2)S)Fe(2)(CO)(6)] moieti...

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Detalles Bibliográficos
Autores principales: Han, Cong, Huang, Xiao-Nan, Guo, Yan-Ling, Liu, Wei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007034/
https://www.ncbi.nlm.nih.gov/pubmed/21587736
http://dx.doi.org/10.1107/S1600536810022634
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author Han, Cong
Huang, Xiao-Nan
Guo, Yan-Ling
Liu, Wei
author_facet Han, Cong
Huang, Xiao-Nan
Guo, Yan-Ling
Liu, Wei
author_sort Han, Cong
collection PubMed
description The title compound, [Fe(4)(C(5)H(5)OS)(2)S(CO)(12)], was prepared by the direct reaction of Fe(3)(CO)(12) and 2-furyl­methane­thiol in tetra­hydro­furan. Desulfurization took place readily to form an Fe(4)S(3) cluster. The mol­ecule consists of two similar [(μ-2-C(4)H(3)O—CH(2)S)Fe(2)(CO)(6)] moieties joined to a spiro-type four-coordinate μ(4)-S atom such that this bridging sulfur is tetra­hedrally coordinated to the four Fe atoms. In each diiron subcluster core, the 2-furyl­methane­thiol­ate ligand bridges the two Fe atoms.
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spelling pubmed-30070342010-12-30 μ(4)-Sulfido-bis­{(μ-2-furyl­methane­thiol­ato)bis­[tricarbonyl­iron](Fe—Fe)} Han, Cong Huang, Xiao-Nan Guo, Yan-Ling Liu, Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Fe(4)(C(5)H(5)OS)(2)S(CO)(12)], was prepared by the direct reaction of Fe(3)(CO)(12) and 2-furyl­methane­thiol in tetra­hydro­furan. Desulfurization took place readily to form an Fe(4)S(3) cluster. The mol­ecule consists of two similar [(μ-2-C(4)H(3)O—CH(2)S)Fe(2)(CO)(6)] moieties joined to a spiro-type four-coordinate μ(4)-S atom such that this bridging sulfur is tetra­hedrally coordinated to the four Fe atoms. In each diiron subcluster core, the 2-furyl­methane­thiol­ate ligand bridges the two Fe atoms. International Union of Crystallography 2010-06-18 /pmc/articles/PMC3007034/ /pubmed/21587736 http://dx.doi.org/10.1107/S1600536810022634 Text en © Han et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Han, Cong
Huang, Xiao-Nan
Guo, Yan-Ling
Liu, Wei
μ(4)-Sulfido-bis­{(μ-2-furyl­methane­thiol­ato)bis­[tricarbonyl­iron](Fe—Fe)}
title μ(4)-Sulfido-bis­{(μ-2-furyl­methane­thiol­ato)bis­[tricarbonyl­iron](Fe—Fe)}
title_full μ(4)-Sulfido-bis­{(μ-2-furyl­methane­thiol­ato)bis­[tricarbonyl­iron](Fe—Fe)}
title_fullStr μ(4)-Sulfido-bis­{(μ-2-furyl­methane­thiol­ato)bis­[tricarbonyl­iron](Fe—Fe)}
title_full_unstemmed μ(4)-Sulfido-bis­{(μ-2-furyl­methane­thiol­ato)bis­[tricarbonyl­iron](Fe—Fe)}
title_short μ(4)-Sulfido-bis­{(μ-2-furyl­methane­thiol­ato)bis­[tricarbonyl­iron](Fe—Fe)}
title_sort μ(4)-sulfido-bis­{(μ-2-furyl­methane­thiol­ato)bis­[tricarbonyl­iron](fe—fe)}
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007034/
https://www.ncbi.nlm.nih.gov/pubmed/21587736
http://dx.doi.org/10.1107/S1600536810022634
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