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1-Benzyl-3-[(trimethyl­sil­yl)meth­yl]benzimidazolium chloride monohydrate

The title compound, C(18)H(23)N(2)Si(+)·Cl(−)·H(2)O, was synthesized from 1-[(trimethyl­sil­yl)meth­yl]benzimidazole and benzyl chloride in dimethyl­formamide. The benzimidazole ring system is approximately planar, with a maximum deviation of 0.022 (2) Å, and makes an angle of 74.80 (12)° with the p...

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Autores principales: Akkurt, Mehmet, Çelik, Ísmail, Küçükbay, Hasan, Şireci, Nihat, Büyükgüngör, Orhan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007035/
https://www.ncbi.nlm.nih.gov/pubmed/21587984
http://dx.doi.org/10.1107/S1600536810024128
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author Akkurt, Mehmet
Çelik, Ísmail
Küçükbay, Hasan
Şireci, Nihat
Büyükgüngör, Orhan
author_facet Akkurt, Mehmet
Çelik, Ísmail
Küçükbay, Hasan
Şireci, Nihat
Büyükgüngör, Orhan
author_sort Akkurt, Mehmet
collection PubMed
description The title compound, C(18)H(23)N(2)Si(+)·Cl(−)·H(2)O, was synthesized from 1-[(trimethyl­sil­yl)meth­yl]benzimidazole and benzyl chloride in dimethyl­formamide. The benzimidazole ring system is approximately planar, with a maximum deviation of 0.022 (2) Å, and makes an angle of 74.80 (12)° with the phenyl ring. The crystal packing is stabilized by O—H⋯Cl, C—H⋯Cl, C—H⋯O and C—H⋯π inter­actions between symmetry-related mol­ecules together with π–π stacking inter­actions between the imidazolium and benzene rings [centroid–centroid distance = 3.5690 (15) Å] and between the benzene rings [centroid–centroid distance = 3.7223 (14) Å].
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spelling pubmed-30070352010-12-30 1-Benzyl-3-[(trimethyl­sil­yl)meth­yl]benzimidazolium chloride monohydrate Akkurt, Mehmet Çelik, Ísmail Küçükbay, Hasan Şireci, Nihat Büyükgüngör, Orhan Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(18)H(23)N(2)Si(+)·Cl(−)·H(2)O, was synthesized from 1-[(trimethyl­sil­yl)meth­yl]benzimidazole and benzyl chloride in dimethyl­formamide. The benzimidazole ring system is approximately planar, with a maximum deviation of 0.022 (2) Å, and makes an angle of 74.80 (12)° with the phenyl ring. The crystal packing is stabilized by O—H⋯Cl, C—H⋯Cl, C—H⋯O and C—H⋯π inter­actions between symmetry-related mol­ecules together with π–π stacking inter­actions between the imidazolium and benzene rings [centroid–centroid distance = 3.5690 (15) Å] and between the benzene rings [centroid–centroid distance = 3.7223 (14) Å]. International Union of Crystallography 2010-06-26 /pmc/articles/PMC3007035/ /pubmed/21587984 http://dx.doi.org/10.1107/S1600536810024128 Text en © Akkurt et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Akkurt, Mehmet
Çelik, Ísmail
Küçükbay, Hasan
Şireci, Nihat
Büyükgüngör, Orhan
1-Benzyl-3-[(trimethyl­sil­yl)meth­yl]benzimidazolium chloride monohydrate
title 1-Benzyl-3-[(trimethyl­sil­yl)meth­yl]benzimidazolium chloride monohydrate
title_full 1-Benzyl-3-[(trimethyl­sil­yl)meth­yl]benzimidazolium chloride monohydrate
title_fullStr 1-Benzyl-3-[(trimethyl­sil­yl)meth­yl]benzimidazolium chloride monohydrate
title_full_unstemmed 1-Benzyl-3-[(trimethyl­sil­yl)meth­yl]benzimidazolium chloride monohydrate
title_short 1-Benzyl-3-[(trimethyl­sil­yl)meth­yl]benzimidazolium chloride monohydrate
title_sort 1-benzyl-3-[(trimethyl­sil­yl)meth­yl]benzimidazolium chloride monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007035/
https://www.ncbi.nlm.nih.gov/pubmed/21587984
http://dx.doi.org/10.1107/S1600536810024128
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