Cargando…
1-Benzyl-3-[(trimethylsilyl)methyl]benzimidazolium chloride monohydrate
The title compound, C(18)H(23)N(2)Si(+)·Cl(−)·H(2)O, was synthesized from 1-[(trimethylsilyl)methyl]benzimidazole and benzyl chloride in dimethylformamide. The benzimidazole ring system is approximately planar, with a maximum deviation of 0.022 (2) Å, and makes an angle of 74.80 (12)° with the p...
Autores principales: | , , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007035/ https://www.ncbi.nlm.nih.gov/pubmed/21587984 http://dx.doi.org/10.1107/S1600536810024128 |
_version_ | 1782194282203971584 |
---|---|
author | Akkurt, Mehmet Çelik, Ísmail Küçükbay, Hasan Şireci, Nihat Büyükgüngör, Orhan |
author_facet | Akkurt, Mehmet Çelik, Ísmail Küçükbay, Hasan Şireci, Nihat Büyükgüngör, Orhan |
author_sort | Akkurt, Mehmet |
collection | PubMed |
description | The title compound, C(18)H(23)N(2)Si(+)·Cl(−)·H(2)O, was synthesized from 1-[(trimethylsilyl)methyl]benzimidazole and benzyl chloride in dimethylformamide. The benzimidazole ring system is approximately planar, with a maximum deviation of 0.022 (2) Å, and makes an angle of 74.80 (12)° with the phenyl ring. The crystal packing is stabilized by O—H⋯Cl, C—H⋯Cl, C—H⋯O and C—H⋯π interactions between symmetry-related molecules together with π–π stacking interactions between the imidazolium and benzene rings [centroid–centroid distance = 3.5690 (15) Å] and between the benzene rings [centroid–centroid distance = 3.7223 (14) Å]. |
format | Text |
id | pubmed-3007035 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30070352010-12-30 1-Benzyl-3-[(trimethylsilyl)methyl]benzimidazolium chloride monohydrate Akkurt, Mehmet Çelik, Ísmail Küçükbay, Hasan Şireci, Nihat Büyükgüngör, Orhan Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(18)H(23)N(2)Si(+)·Cl(−)·H(2)O, was synthesized from 1-[(trimethylsilyl)methyl]benzimidazole and benzyl chloride in dimethylformamide. The benzimidazole ring system is approximately planar, with a maximum deviation of 0.022 (2) Å, and makes an angle of 74.80 (12)° with the phenyl ring. The crystal packing is stabilized by O—H⋯Cl, C—H⋯Cl, C—H⋯O and C—H⋯π interactions between symmetry-related molecules together with π–π stacking interactions between the imidazolium and benzene rings [centroid–centroid distance = 3.5690 (15) Å] and between the benzene rings [centroid–centroid distance = 3.7223 (14) Å]. International Union of Crystallography 2010-06-26 /pmc/articles/PMC3007035/ /pubmed/21587984 http://dx.doi.org/10.1107/S1600536810024128 Text en © Akkurt et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Akkurt, Mehmet Çelik, Ísmail Küçükbay, Hasan Şireci, Nihat Büyükgüngör, Orhan 1-Benzyl-3-[(trimethylsilyl)methyl]benzimidazolium chloride monohydrate |
title | 1-Benzyl-3-[(trimethylsilyl)methyl]benzimidazolium chloride monohydrate |
title_full | 1-Benzyl-3-[(trimethylsilyl)methyl]benzimidazolium chloride monohydrate |
title_fullStr | 1-Benzyl-3-[(trimethylsilyl)methyl]benzimidazolium chloride monohydrate |
title_full_unstemmed | 1-Benzyl-3-[(trimethylsilyl)methyl]benzimidazolium chloride monohydrate |
title_short | 1-Benzyl-3-[(trimethylsilyl)methyl]benzimidazolium chloride monohydrate |
title_sort | 1-benzyl-3-[(trimethylsilyl)methyl]benzimidazolium chloride monohydrate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007035/ https://www.ncbi.nlm.nih.gov/pubmed/21587984 http://dx.doi.org/10.1107/S1600536810024128 |
work_keys_str_mv | AT akkurtmehmet 1benzyl3trimethylsilylmethylbenzimidazoliumchloridemonohydrate AT celikismail 1benzyl3trimethylsilylmethylbenzimidazoliumchloridemonohydrate AT kucukbayhasan 1benzyl3trimethylsilylmethylbenzimidazoliumchloridemonohydrate AT sirecinihat 1benzyl3trimethylsilylmethylbenzimidazoliumchloridemonohydrate AT buyukgungororhan 1benzyl3trimethylsilylmethylbenzimidazoliumchloridemonohydrate |