(Acetato-κ(2) O,O′)bis­(1,10-phenanthroline-κ(2) N,N′)copper(II) trifluoro­acetate tetra­hydrate

In the title compound, [Cu(CH(3)CO(2))(C(12)H(8)N(2))(2)](CF(3)CO(2))·4H(2)O, the Cu(II) atom shows a distorted octa­hedral coordination with four N atoms [Cu—N = 2.015 (3)–2.244 (3) Å] from the two phenanthroline ligands and two O atoms from the acetate [Cu—O = 1.953 (3) and 2.764 (3) Å]. Strong in...

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Detalles Bibliográficos
Autores principales: Wang, Jinxia, Jin, Zhuping
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007037/
https://www.ncbi.nlm.nih.gov/pubmed/21587769
http://dx.doi.org/10.1107/S1600536810024359
Descripción
Sumario:In the title compound, [Cu(CH(3)CO(2))(C(12)H(8)N(2))(2)](CF(3)CO(2))·4H(2)O, the Cu(II) atom shows a distorted octa­hedral coordination with four N atoms [Cu—N = 2.015 (3)–2.244 (3) Å] from the two phenanthroline ligands and two O atoms from the acetate [Cu—O = 1.953 (3) and 2.764 (3) Å]. Strong inter­molecular O—H⋯O hydrogen-bonding inter­actions consolidate the crystal packing. The F atoms of the anion are disordered over two positions in a 0.5233 (3):0.4767 (3) ratio.

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