(Acetato-κ(2) O,O′)bis­(1,10-phenanthroline-κ(2) N,N′)copper(II) trifluoro­acetate tetra­hydrate

In the title compound, [Cu(CH(3)CO(2))(C(12)H(8)N(2))(2)](CF(3)CO(2))·4H(2)O, the Cu(II) atom shows a distorted octa­hedral coordination with four N atoms [Cu—N = 2.015 (3)–2.244 (3) Å] from the two phenanthroline ligands and two O atoms from the acetate [Cu—O = 1.953 (3) and 2.764 (3) Å]. Strong in...

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Detalles Bibliográficos
Autores principales: Wang, Jinxia, Jin, Zhuping
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007037/
https://www.ncbi.nlm.nih.gov/pubmed/21587769
http://dx.doi.org/10.1107/S1600536810024359
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author Wang, Jinxia
Jin, Zhuping
author_facet Wang, Jinxia
Jin, Zhuping
author_sort Wang, Jinxia
collection PubMed
description In the title compound, [Cu(CH(3)CO(2))(C(12)H(8)N(2))(2)](CF(3)CO(2))·4H(2)O, the Cu(II) atom shows a distorted octa­hedral coordination with four N atoms [Cu—N = 2.015 (3)–2.244 (3) Å] from the two phenanthroline ligands and two O atoms from the acetate [Cu—O = 1.953 (3) and 2.764 (3) Å]. Strong inter­molecular O—H⋯O hydrogen-bonding inter­actions consolidate the crystal packing. The F atoms of the anion are disordered over two positions in a 0.5233 (3):0.4767 (3) ratio.
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spelling pubmed-30070372010-12-30 (Acetato-κ(2) O,O′)bis­(1,10-phenanthroline-κ(2) N,N′)copper(II) trifluoro­acetate tetra­hydrate Wang, Jinxia Jin, Zhuping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(CH(3)CO(2))(C(12)H(8)N(2))(2)](CF(3)CO(2))·4H(2)O, the Cu(II) atom shows a distorted octa­hedral coordination with four N atoms [Cu—N = 2.015 (3)–2.244 (3) Å] from the two phenanthroline ligands and two O atoms from the acetate [Cu—O = 1.953 (3) and 2.764 (3) Å]. Strong inter­molecular O—H⋯O hydrogen-bonding inter­actions consolidate the crystal packing. The F atoms of the anion are disordered over two positions in a 0.5233 (3):0.4767 (3) ratio. International Union of Crystallography 2010-06-30 /pmc/articles/PMC3007037/ /pubmed/21587769 http://dx.doi.org/10.1107/S1600536810024359 Text en © Wang and Jin 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Jinxia
Jin, Zhuping
(Acetato-κ(2) O,O′)bis­(1,10-phenanthroline-κ(2) N,N′)copper(II) trifluoro­acetate tetra­hydrate
title (Acetato-κ(2) O,O′)bis­(1,10-phenanthroline-κ(2) N,N′)copper(II) trifluoro­acetate tetra­hydrate
title_full (Acetato-κ(2) O,O′)bis­(1,10-phenanthroline-κ(2) N,N′)copper(II) trifluoro­acetate tetra­hydrate
title_fullStr (Acetato-κ(2) O,O′)bis­(1,10-phenanthroline-κ(2) N,N′)copper(II) trifluoro­acetate tetra­hydrate
title_full_unstemmed (Acetato-κ(2) O,O′)bis­(1,10-phenanthroline-κ(2) N,N′)copper(II) trifluoro­acetate tetra­hydrate
title_short (Acetato-κ(2) O,O′)bis­(1,10-phenanthroline-κ(2) N,N′)copper(II) trifluoro­acetate tetra­hydrate
title_sort (acetato-κ(2) o,o′)bis­(1,10-phenanthroline-κ(2) n,n′)copper(ii) trifluoro­acetate tetra­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007037/
https://www.ncbi.nlm.nih.gov/pubmed/21587769
http://dx.doi.org/10.1107/S1600536810024359
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